Lead(IV) acetate, 96% (dry wt.), stab. with 5-10% glacial acetic acid

CAS: 546-67-8

Ref. 02-A15551

Product Information

• Name: Lead(IV) acetate, 96% (dry wt.), stab. with 5-10% glacial acetic acid
• Synonyms: lead(IV) acetate, Acetate, Lead (Iv), Acetate, Lead(2+) Salt (4:1), Acetic acid, lead(4+) salt, Acetic acid, lead(4+) salt (4:1), Bleitetraacetat, LTA, Lead (II) acetate, Lead Tetracetate, Lead acetate (Pb(O2C2H3)4), Lead acetate (Pb(O₂C₂H₃)₄), Lead acetate [Pb(OAc)4], Lead acetate [Pb(OAc)₄], Lead tetraacetate, Lead(4+) acetate, Lead(IV) acetate (5-10% acetic acid), Lead(IV) tetraacetate, Leadacetateaceticacidwhitetolightbrownxtl, Plumbic acetate, Tetraacetate de plomb, Tetraacetato De Plomo

Description

Lead(IV) acetate is an important oxidizing agent and a source of acetyloxy group used in organic synthesis. For example, 1,4-dioxene is prepared from dioxane involving 2-acetoxy-1,4-dioxane as an intermediate. Similarly, it is used for the preparation of bis(trifluoromethyl)diazomethane from hexafluoroacetone hydrazone. It also reacts with alkenes, alcohols having a delta-proton and di-n-butyl d-tartrate to get gamma-lactones, cyclic ethers and n-butyl glyoxylate respectively. It induces the cleavage of 1,2-diols to the corresponding aldehydes or ketones. It is actively involved in the Kochi reaction for the decarboxylation of carboxylic acids to alkyl halides and used as an alternative reagent to bromine in the Hofmann rearrangement. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Brand: Alfa Aesar By Thermo Fisher Scientific

Chemical properties

• Molecular weight: 443.40
• Formula: C₈H₁₂O₈Pb
• Purity: 96%
• Color/Form: Moist crystals or powder or crystalline powder, White to pale cream or pale grey
• InChI key: ACKFDYCQCBEDNU-UHFFFAOYSA-J