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2-Chloro-1,3-dimethylimidazolinium hexafluorophosphate

CAS: 101385-69-7

Ref. 10-009079

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Estimated delivery in United States, on Tuesday 28 Jul 2020

Product Information

Name:
2-Chloro-1,3-dimethylimidazolinium hexafluorophosphate
Description:

009079 - 2-Chloro-1,3-dimethylimidazolinium hexafluorophosphate

Notes:

An effective coupling reagent for peptide synthesis. Used in preparation of a glycosylated bicyclic peptide -MEN11420 by double cyclization,1 convergent synthesis of dolastatin 15 by solid phase coupling of N-methylamino acid,2 convergent synthesis of (-)-mirabazole B in the presence of 1-hydroxy-7- azabenzotriazole (HOAt),3 and efficient coupling of α,α-dimethyl amino acids.4 Also employed in the synthesis of 2-azido-1,3-dimethylimidazolinium hexafluorophosphate for preparing organic azides from primary amines.5  1.        Peptides 2000, Proceedings of the European Peptide Symposium, 2000, 183. 2.        Pept. Sci. 1999, 35, 9. 3.        J. Org. Chem. 1999, 64, 405. 4.        Tetrahedron 1997, 53, 8323. 5.        Eur. J. Org. Chem. 2011, 3, 458.


Chemical properties

MDL:
MFCD00191914
Molecular weight:
278.56
Formula:
C5H10ClF6N2P
Purity:
98%

Hazard Info

H Statements:
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
P Statements:
P233: Keep container tightly closed.
P260: Do not breathe dust, fumes, gas, mist, vapours, spray.
P261: Avoid breathing dust, fumes, gas, mist, vapours, spray. [As modified by IV ATP].
P264: Wash thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN:  Wash with plenty of soap and water. 
P304: IF INHALED:
P304+P340: IF INHALED:  Remove person to fresh air and keep comfortable for breathing. 
P305+P351+P338: IF IN EYES:  Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. 
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see label).
P332+P313: If skin irritation occurs:  Get medical advice/attention. 
P337+P313: If eye irritation persists:  Get medical advice/attention. 
P340: Remove person to fresh air and keep comfortable for breathing.
P362: Take off contaminated clothing. [As modified by IV ATP].
P403: Store in a well ventilated place.
P403+P233: Store in a well ventilated place. Keep container tightly closed. 
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

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