(Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-KappaN,KappaP](Eta5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate

CAS: 930601-66-4

Ref. TR-A164155

Product Information

• Name: (Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-KappaN,KappaP](Eta5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate
• Synonyms: Alkene Zipper Catalyst
• CAS: 930601-66-4

Description

Applications (Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-κN,κP](η5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate, is an Alkene Zipper Catalyst, used in selective transformation of a large variety of ω-alkenyl cyclopropylcarbinols into stereodefined unconjugated (E)-acyclic aldehydes .
References Bruffaerts, J., Vasseur, A., & Marek, I. (2018). Alkene-Zipper Catalyzed Selective and Remote Retro-ene Reaction of Alkenyl Cyclopropylcarbinol. Advanced Synthesis & Catalysis, 360(7), 1389-1396.

• Brand: TRC

Chemical properties

• Molecular weight: 606.53
• Formula: C₂₁H₃₅N₃PRu•PF₆
• Color/Form: Clear Colorless to Pale Yellow Oil
• InChI: InChI=1S/C15H27NP.C5H10.C2H5N.F5P.FH.Ru/c1-11(2)17(12(3)4)14-9-13(10-16(14)8)15(5,6)7;1-2-4-5-3-1;1-2-3;1-6(2,3,4)5;;/h10-12H,1-8H3;1-5H2;2-3H,1H3;;1H