[((R,R)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)(η6-p-cymene)ruthenium

CAS: 192139-92-7

Ref. TR-A618635

Product Information

• Name: [((R,R)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)(η6-p-cymene)ruthenium
• Synonyms: [R-(R*,R*)]-[N-[2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium, [N-[(1R,2R)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium, [N-[(1R,2R)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-4-(1-methylethyl)benzene]-ruthenium, RuCl(p-cymene)[(R,R)-Ts-DPEN], Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
• CAS: 192139-92-7

Description

Applications [((R,R)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)(η6-p-cymene)ruthenium is an catalyst used for enantioselective hydrogenation of quinolines, N-Alky Ketimines and antitumor, antiproliferative derivatives of natural products isolated from bacteria.
References Son, S.M., et al.: J. Org. Chem., 79, 2666 (2014); Liu, Y., et al.: J. Org. Chem., 78, 12009 (2013); Fang, Z.J., et al.: J. Org. Chem., 78, 8594 (2013);

• Brand: TRC

Chemical properties

• Molecular weight: 636.21
• Formula: C₃₁H₃₅ClN₂O₂RuS
• Color/Form: Dark Orange to Very Dark Orange Solid
• InChI: InChI=1S/C21H21N2O2S.C10H20.CH3.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;;/h2-15,20-21H,22H2,1H3;8-10H,4-7H2,1-3H3;1H3;1H;/q-1;;;;+2/p-1/t20-,21-;9-,10+;;;/m1..../s1
• InChI key: InChIKey=DLXVACIQQGGZRV-UXHLDNHASA-M