(1R,3R,4R)-(-)-3,5-Dinitrobenzoate Menthol

CAS: 1195710-85-0

Ref. TR-D480025

Informação sobre produto

• Nome: (1R,3R,4R)-(-)-3,5-Dinitrobenzoate Menthol
• Sinónimos: 7-[(2S,5R)-6-[[tert-butyl(diphenyl)silyl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-4-methylchromen-2-one
• Marca: TRC
• Descrição: Applications (1S,3S,4S)-(-)-3,5-dinitrobenzoate Menthol is an intermediate in the synthesis of (±)-Neoisomenthol (N389960) which is a useful synthetic intermediate. It is used to prepare alkyl and aryl esters by chemoselective acylation of alkyl and aryl alcohols with carboxylic acid anhydrides in the presence of magnesium bis(trifluoromethylsulfonyl)amide under solvent-free conditions.References Chakraborti, A., et al.: J. Org. Chem., 71, 5785 (2006)

Propriedades químicas

• Peso molecular: 576.709
• Fórmula: C₃₂H₃₆O₈Si
• Cor/forma: Neat
• InChI: InChI=1S/C32H36O8Si/c1-20-17-27(33)39-25-18-21(15-16-24(20)25)38-31-30(36)29(35)28(34)26(40-31)19-37-41(32(2,3)4,22-11-7-5-8-12-22)23-13-9-6-10-14-23/h5-18,26,28-31,34-36H,19H2,1-4H3/t26?,28-,29?,30?,31+/m0/s1
• Chave InChI: InChIKey=YTHDSJIOVBDTQV-OFMPIAEOSA-N
• SMILES: Cc1cc(=O)oc2cc(O[C@@H]3OC(CO[Si](c4ccccc4)(c4ccccc4)C(C)(C)C)[C@H](O)C(O)C3O)ccc12