CAS 498-07-7

1,6-Anhydro-β-D-Glucose

Beschreibung:

1,6-Anhydro-β-D-Glucose ist ein zyklisches Zuckerdérivat, das durch seine einzigartige Struktur gekennzeichnet ist, die einen sechsgliedrigen Ring aufweist, der durch die Dehydratisierung von zwei Hydroxylgruppen an den Positionen 1 und 6 von β-D-Glukose gebildet wird. Diese Verbindung ist ein weißes kristallines Feststoff, das in Wasser löslich ist, was ihre polare Natur aufgrund der Anwesenheit von Hydroxylgruppen widerspiegelt. Sie kommt häufig in verschiedenen natürlichen Polysacchariden vor, insbesondere in der Struktur bestimmter Pflanzenmaterialien und als Produkt des Zelluloseabbaus. Die anhydrische Form zeigt an, dass ihr ein Wassermolekül fehlt, das normalerweise in ihrer hydratisierten Form vorhanden wäre, was ihre Reaktivität und Stabilität beeinflusst. 1,6-Anhydro-β-D-Glucose kann an verschiedenen chemischen Reaktionen teilnehmen, einschließlich Glykosylierung und Oxidation, was sie sowohl für biochemische als auch industrielle Anwendungen von Interesse macht. Ihre Rolle in der Kohlenhydratchemie und die potenziellen Anwendungen in der Pharmazie und Lebensmittelwissenschaft unterstreichen ihre Bedeutung in sowohl natürlichen als auch synthetischen Prozessen.

Formel: C₆H₁₀O₅

InChl: InChI=1/C6H10O5/c7-3-2-1-10-6(11-2)5(9)4(3)8/h2-9H,1H2/t2-,3+,4-,5+,6-/m0/s1

InChI Key: InChIKey=TWNIBLMWSKIRAT-VFUOTHLCSA-N

SMILES: O[C@@H]1[C@@]2(O[C@@](OC2)([C@H](O)[C@H]1O)[H])[H]

Synonyme:

• 1,6-Anhydro-<span class="text-smallcaps">D</span>-glucopyranoside
• 1,6-Anhydro-<span class="text-smallcaps">D</span>-glucose
• 1,6-Anhydro-Beta-D-Glucopyranose
• 1,6-Anhydro-D-glucopyranoside
• 1,6-Anhydro-D-glucose
• 1,6-Anhydro-β-<span class="text-smallcaps">D</span>-glucopyranose
• 1,6-Anhydro-β-<span class="text-smallcaps">D</span>-glucose
• 1,6-Anhydro-β-D-glucopyranose
• 1,6-Anhydroglucose
• 1,6-anhidro-β-D-glucosa
• 6,8-Dioxabicyclo[3.2.1]octane, β-<span class="text-smallcaps">D</span>-glucopyranose deriv.
• <span class="text-smallcaps">D</span>-Glucose, 1,6-anhydro-
• D-Glucose, 1,6-anhydro-
• GLUCOPYRANOSE (,beta.-D), 1,6-ANHYDRO-
• Leucoglucosan
• Levoglucosan
• Nsc 46243
• β-<span class="text-smallcaps">D</span>-Glucopyranose, 1,6-anhydro-
• β-D-Glucopyranose, 1,6-anhydro-
• 6,8-Dioxabicyclo[3.2.1]octane, β-D-glucopyranose deriv.
• (-)-1,6-ANHYDRO-B-D-GLUCOPYRANOSE FOR SY
• 1,6-Anhydro-beta-D-glucopyranose, 99+%
• 1,6-Anhydro-β-D-glucose ,98%
• 1,6-Anhydro-?-glucopyranose
• 1,6-anhydro-á-d-glucopyranose
• 1,6-ANHYDRO-SS-D-GLUCOPYRANOSE, 99% MIN., HPLC
• 1,6-anhydro-β-d-[1-2H]glucose
• beta-D-Glucopyranose, 1,6-anhydro-
• Laevoglucosan
• 1,6-Anhydro-beta-D-glucopyranose (levoglucosan)
• 1,6-Anhydro-D-glucopyranose, 99℉
• 1,6-Anhydro-
• 1,6-Anhydro-β-D-glucose,Levoglucosan
• (-)-1,6-Anhydro--D-glucopyranose for synthesis
• 1,6-Anhydro-beta-D-glucopyranose min. 98%
• 1,6-Anhydro-β-D-glycopyranose
• 1,6-Anhydro-beta-D-glucose 99%
• 1,6-ANHYDRO-BETA-D-GLUCOSE (LEVOGLUCOSAN)
• 1,6-ANHYDRO-SS-D-GLUCOPYRANOSE
• 1,6-anhydro-beta-glucopyranose
• 1,6-ANHYDRO-BETA-D-GLUCOPYRA
• 1,6-ANHYDRO-BETA-D-GLUCOSE
• 1,6-anhydro-β-d-[UL-2H7]glucose
• 1,6-anhydro-beta-d-glucopyranos
• 1,6-anhydro-D-glucose (50 mg)
• 1,6-Dideoxy-1,6-epoxy-β-D-glucopyranose
• 1,6-Anhydro-β-glucopyranose
• 1,6-ANHYDRO-B-D-GLUCOSE

1,6-Anhydro-β-D-glucose

CAS: 498-07-7

Formel: C₆H₁₀O₅

Reinheit: >99.0%(GC)

Farbe und Form: White to Light yellow powder to crystal

Molekulargewicht: 162.14

Ref: 3B-A1074

1,6-Anhydro-β-D-glucopyranose, 99%

CAS: 498-07-7

1,6-Anhydro-beta-D-glucopyranose is used for the preparation of biologically important and structurally diverse products such as rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, macrolide antibiotics and modified sugars. It is used as a chemical tracer for biomass burning

Formel: C₆H₁₀O₅

Reinheit: 99%

Farbe und Form: Powder or crystals or crystalline powder, White

Molekulargewicht: 162.14

Ref: 02-A16724

1,6-anhydro-D-glucose

CAS: 498-07-7

Heterocyclic compounds with oxygen hetero-atom(s) only, nesoi

Formel: C₆H₁₀O₅

Farbe und Form: White Beige Powder

Molekulargewicht: 162.05282

Ref: 45-1035300

b-D-Glucopyranose, 1,6-anhydro-

CAS: 498-07-7

Formel: C₆H₁₀O₅

Reinheit: 98%

Farbe und Form: Solid

Molekulargewicht: 162.1406

Ref: IN-DA00I8WB

1,6-Anhydro-β-D-glucopyranose

CAS: 498-07-7

1,6-Anhydro-β-D-glucopyranose

Formel: C₆H₁₀O₅

Reinheit: 98%

Farbe und Form: Beige Solid

Molekulargewicht: 162.1406

Ref: 54-OR4810T

Levoglucosan

CAS: 498-07-7

Levoglucosan

Formel: C₆H₁₀O₅

Reinheit: ≥95%

Molekulargewicht: 162.14

Ref: 54-BUP18060

Levoglucosan

Kontrolliertes Produkt

CAS: 498-07-7

Formel: C₆H₁₀O₅

Farbe und Form: Neat

Molekulargewicht: 162.14

Ref: 04-C14629735

Levoglucosan (Standard)

CAS: 498-07-7

Levoglucosan (Standard) is the standard substance of Levoglucosan, and it is applicable for quantitative analysis, quality control, and related research in biochemical experiments. Levoglucosan (1,6-anhydro-b-D-Glucose) is an anhydrohexose that is the 1,6-anhydro-derivative of beta-D-glucopyranose. It is formed from the pyrolysis of carbohydrates, such as starch and cellulose. Levoglucosan can also be utilized in the synthesis of chiral polymers such as unhydrolysable glucose polymers. Levoglucosan is also produced via caramelization of sugar. Consumption of caramel or caramel-containing sweets can lead to a short-term 5X increase in urinary levels of levoglucosan (from 20 uM/mM creatinine to 100 uM/mM creatinine).

Formel: C₆H₁₀O₅

Farbe und Form: Solid

Molekulargewicht: 162.14

Ref: TM-TMSM-1457

Levoglucosan

CAS: 498-07-7

Levoglucosan is a byproduct of carbohydrate pyrolysis, used in chiral polymer synthesis, and increases in urine post-caramel consumption.

Formel: C₆H₁₀O₅

Reinheit: 99.92% - ≥95%

Farbe und Form: Solid

Molekulargewicht: 162.14

Ref: TM-T5250

1,6-Anhydro-β-D-glucopyranose

CAS: 498-07-7

1,6-Anhydro-β-D-glucopyranose

Formel: C₆H₁₀O₅

Reinheit: 98%

Farbe und Form: Solid-Powder

Molekulargewicht: 162.1406

Ref: 54-BICL4018

1,6-Anhydro-β-D-glucopyranose

CAS: 498-07-7

Formel: C₆H₁₀O₅

Reinheit: (HPLC) ≥ 99.0%

Farbe und Form: White crystalline powder

Molekulargewicht: 162.14

Ref: 7W-GC5907

1,6-Anhydro-β-D-glucopyranose

CAS: 498-07-7

Stability Hygroscopic
Applications 1,6-Anhydrohexopyranoses have proven to be valuable synthons for the preparation of biologically important and structurally diverse products (e.g. rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, and macrolide antibiotics) as well as for modified sugars.The chemical/physical/toxicological properties have not been thoroughly investigated. Since it is known to be a minor component of certain food materials it may be regarded as of relatively low toxicity.
References Fraser-Reid, B., et al. J. Am. Chem. Soc. 106, 731 (1984); Edwards, M.P., et al. J. Org. Chem. 49, 3503 (1984); Kelly, A.G., and Roberts, J.S. J. Chem. Soc., Chem. Commun. 228, (1980); Ogawa, T., et al. Carbohydr. Res. 57, C31 (1977); Isobe, M., et al. Tetrahedron Lett. 28, 6485 (1987); Fresnos, J.N. and Swenton, J.S. , J. Chem. Soc., Chem. Commun. 658, (1985); Kochetkov, N.K. et al., Tetrahedron Lett. 22, 4315, 4319 (1981); Georges, M. et al., Carbohydr. Res. 130, 115 (1984); Paulsen, et al., Chem. Ber. 114, 322 (1981).

Formel: C₆H₁₀O₅

Farbe und Form: Neat

Molekulargewicht: 162.14

Ref: TR-A648100

1,6-Anhydro-beta-D-glucopyranose

CAS: 498-07-7

Used for preparation of biologically active compounds

Formel: C₆H₁₀O₅

Reinheit: Min. 98 Area-%

Farbe und Form: White Powder

Molekulargewicht: 162.14 g/mol

Ref: 3D-ML06636

1,6-Anhydro-β-d-glucose

CAS: 498-07-7

Formel: C₆H₁₀O₅

Reinheit: 95%

Farbe und Form: Solid, Light beige powder

Molekulargewicht: 162.053

Ref: 10-F046709