CAS 14647-23-5

(Bis(difenilfosfino)etano)dicloro níquel

Descripción:

(Bis(difenilfosfino)etano)dicloro níquel, comúnmente conocido como NiCl2(dppeth), es un compuesto de coordinación que presenta níquel en un estado de oxidación +2 coordinado a dos ligandos de difenilfosfinoetano y dos iones de cloruro. Este compuesto típicamente exhibe una geometría cuadrada plana debido a la configuración electrónica d8 del níquel, que es característica de muchos complejos de níquel(II). Los ligandos de difenilfosfinoetano contribuyen a la estabilidad y solubilidad general del complejo en disolventes orgánicos. NiCl2(dppeth) se utiliza a menudo en catálisis, particularmente en reacciones de acilo cruzado y otras transformaciones orgánicas, debido a su capacidad para facilitar la transferencia de electrones y promover la formación de enlaces. La presencia de átomos donadores de fósforo mejora la reactividad del centro de níquel, convirtiéndolo en un compuesto importante en la química organometálica. Además, el compuesto puede exhibir propiedades térmicas y fotocatalíticas interesantes, que pueden ser relevantes en diversas aplicaciones, incluida la ciencia de materiales y la catálisis.

Fórmula: C₂₆H₂₄Cl₂NiP₂

InChI: InChI=1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

Clave InChI: InChIKey=XXECWTBMGGXMKP-UHFFFAOYSA-L

SMILES: [Cl-][Ni+2]1([Cl-])[P](CC[P]1(C2=CC=CC=C2)C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5

Sinónimos:

• (Bis(diphenylphosphino)ethane)dichloronickel
• 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
• 1,2-Bis(diphenylphosphino)ethanedichloronickel
• 1,2-Bis(diphenylphosphino)ethanenickel dichloride
• 1,2-Ethylenebis(diphenylphosphine)nickel dichloride
• DPPE.NiCl2
• Dichloro-1,2-bis(diphenylphosphino)ethanenickel(II)
• Dichloro[1,2-bis(diphenylphosphino)ethane]nickel
• Dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II)
• Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P′]nickel
• Dichloro[1,2-ethanediylbis[diphenylphosphine]]nickel
• Dichloro[ethylenebis[diphenylphosphine]]nickel
• Dichlorobis[(diphenylphosphino)ethane]nickel(II)
• Nickel 1,2-Bis(diphenylphosphino)ethane dichloride
• Nickel, dichloro[1,2-ethanediylbis[diphenylphosphine-κP]]-, (SP-4-2)-
• Nickel, dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P′]-, (SP-4-2)-
• Nickel, dichloro[ethylenebis[diphenylphosphine]]-
• Nickel, dichloro[ethylenebis[diphenylphosphine]]-, cis-
• Phosphine, 1,2-ethanediylbis[diphenyl-, nickel complex
• [1,2-Bis(Diphenylphosphino)Ethane]Dichloronickel(Ii)
• [1,2-Bis(diphenylphosphino)ethane]dichloronickel

[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride

CAS: 14647-23-5

Fórmula: C₂₆H₂₄Cl₂NiP₂

Pureza: >96.0%(T)

Forma y color: Orange to Amber to Dark red powder to crystal

Peso molecular: 528.02

Ref: 3B-B2225

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98%

CAS: 14647-23-5

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols

Fórmula: C₂₆H₂₄Cl₂NiP₂

Pureza: 98%

Forma y color: Orange-red to brown, Powder

Peso molecular: 528.02

Ref: 02-013932

1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride

CAS: 14647-23-5

Fórmula: C₂₆H₂₄Cl₂NiP₂

Pureza: 98%

Forma y color: Solid

Peso molecular: 528.0157

Ref: IN-DA0032KC

1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride

CAS: 14647-23-5

1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride

Pureza: 98%

Peso molecular: 528.02g/mol

Ref: 54-IN10319

[Bis(diphenylphosphino)ethane]dichloronickel

Producto controlado

CAS: 14647-23-5

Applications [Bis(diphenylphosphino)ethane]dichloronickel is a coordination complex with potential antitumor activity. It is also used as a fast and efficient hydrogen production catalyst.
References Mirabelli, C.K., et al.: J. Med. Chem., 30, 2181 (1987); Gan, L., et al.: J. Am. Chem. Soc., 137, 1109 (2015)

Fórmula: C₂₆H₂₄Cl₂NiP₂

Forma y color: Neat

Peso molecular: 528.02

Ref: TR-B430455

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

CAS: 14647-23-5

Fórmula: C₂₆H₂₄Cl₂NiP₂

Pureza: 96%

Forma y color: Solid, Yellow red - deep yellow red powder

Peso molecular: 526.008

Ref: 10-F077791

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride, 99%

CAS: 14647-23-5

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride, 99%

Fórmula: (C₆H₅)₂PCH₂CH₂P(C₆H₅)₂NiCl₂

Pureza: 99%

Forma y color: orange xtl.

Peso molecular: 528.04

Ref: 08-28-0030

[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride

CAS: 14647-23-5

Bis-diphenylphosphinoethane nickel dichloride is a compound that is used for the preparation of other compounds, such as phosphine ligands. Bis-diphenylphosphinoethane nickel dichloride is a solid form of nickel chloride with two crystalline polymorphs, one with a monoclinic crystal structure and the other with a tetragonal crystal structure. In order to obtain the desired product, it must be prepared in an orientational process and synthesised at low temperatures. Bis-diphenylphosphinoethane nickel dichloride has been shown to have anti-cancer properties.br>br> Bis-diphenylphosphinoethane nickel dichloride has also been used to prepare other compounds by cross coupling reactions. This method is effective for preparing compounds that are difficult to make using conventional methods, such as organometallic complexes.br>br> Bis-d

Fórmula: C₂₆H₂₄Cl₂NiP₂

Pureza: Min. 95%

Peso molecular: 528.02 g/mol

Ref: 3D-FB60935