CAS 657408-07-6

2-Diciclohexilfosfino-2',6'-dimetoxibifenilo

Descripción:

2-Diciclohexilfosfino-2',6'-dimetoxibifenilo es un ligando de fosfina comúnmente utilizado en química organometálica y catálisis, particularmente en complejos de metales de transición. Este compuesto presenta un esqueleto de bifenilo con sustituyentes metóxicos en las posiciones 2 y 6, lo que mejora su solubilidad y propiedades estéricas. El grupo dicyclohexilfosfino proporciona características de donante fuertes, lo que lo hace efectivo para estabilizar centros metálicos en reacciones catalíticas. La presencia de grupos ciclopentilo voluminosos contribuye a su impedimento estérico, lo que puede influir en la selectividad y reactividad de los complejos metálicos. Este ligando se emplea a menudo en reacciones de acilo cruzado, como las reacciones de Suzuki o Heck, debido a su capacidad para facilitar la formación de enlaces carbono-carbono. Además, sus características estructurales únicas permiten ajustar las propiedades electrónicas, lo que lo convierte en una herramienta valiosa en el desarrollo de nuevos sistemas catalíticos. En general, 2-Diciclohexilfosfino-2',6'-dimetoxibifenilo es reconocido por su efectividad en la promoción de diversas transformaciones químicas en la química orgánica sintética.

Fórmula: C₂₆H₃₅O₂P

InChI: InChI=1S/C26H35O2P/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21/h9-11,16-21H,3-8,12-15H2,1-2H3

Clave InChI: InChIKey=VNFWTIYUKDMAOP-UHFFFAOYSA-N

SMILES: P(C1=C(C=CC=C1)C2=C(OC)C=CC=C2OC)(C3CCCCC3)C4CCCCC4

Sinónimos:

• (2,6-Dimethoxy-1,1′-biphenyl-2-yl)dicyclohexylphosphine
• 2-(Dicyclohexylphosphino)-2′,6′-dimethoxy-1,1′-biphenyl
• 2-Dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl
• 2-Dicyclohexylphosphino-2',6'-dimethoxybipheny
• 2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl
• Dicyclohexyl(2',6'-Dimethoxybiphenyl-2-Yl)Phosphane
• Dicyclohexyl(2′,6′-dimethoxy[1,1′-biphenyl]-2-yl)phosphine
• Dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine
• Dicyclohexyl({2-[(2,6-Dimethoxyphenyl)Methyl]Phenyl}Methyl)Phosphane
• Phosphine, dicyclohexyl(2′,6′-dimethoxy[1,1′-biphenyl]-2-yl)-
• S-Phos
• SPhos 97%
• 2-Dicyclohexylphosphino-2',6'-diMethoxy-1,1'-biphenyl,98% Sphos
• 2-DicyclohexylphosphiNA-2',6'-diMethoxybiphenyl
• Dicyclohexyl(2',6'-dimethoxybiphenyl-2-yl)phosphine
• 2-Dicyclohexylphosphino-2&acute
• REF DUPL: S-PHOS
• 2 - dicyclohexyl phosphine - 2 ', 6 '- diMethoxy - 1, 1' - two PCB
• S-Phos, ChemDose(R) tablets
• S-Phos impregnated tablets, ChemDose(R), S-Phos tablets, 2-Dicyclohexylphosphino-2μ,6μ-dimethoxybiphenyl impregnated tablets
• 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl
• 6&acute
• 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl, min. 98%
• 98% SPhos
• 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 98+%
• 2-Dicyclohexylphosphino-2’,6’-dimethoxy-1,1’-biphenyl (S-Phos)
• S-PHOS, 2-Dicyclohexylphosphino-2,6-di-Methyloxy-1,1-biphenyl
• Phosphine,dicyclohexyl(2',6'-dimethoxy[1,1'-biphenyl]-2-yl)-
• 2-Dicyclohexylphosphino-2', 6-diMethoxybihenyl
• 2-DICYCLOHEXYLPHOSPHINO-2',6'-DIMETHOXY-1,1'-BIPHENYL, MIN. 98% S-PHOS
• 2-Dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl, min. 98%
• 2-(Dicyclohexylphosphanyl)-2',6'-dimethoxybiphenyl
• 2-Dicyclohexylphosphino-2',6'-diMethoxybiphenyl, 6'-diMethoxybiphenyl
• SPhos, >=98%
• 2-Dicyclohexylphosphino-2',6'-
• S-Phos, ChemDose? tablets
• -diMethoxybiphenyl
• Dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane
• Dicyclohexyl(2',6'-diMethoxy-[1,1'-biphenyl]-2-yl)phosphine

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

CAS: 657408-07-6

Fórmula: C₂₆H₃₅O₂P

Pureza: >98.0%(HPLC)

Forma y color: White to Almost white powder to crystal

Peso molecular: 410.54

Ref: 3B-D5036

2-Dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl, min. 98% SPhos

CAS: 657408-07-6

2-Dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl, min. 98% SPhos

Fórmula: C₂₆H₃₅O₂P

Pureza: min. 98%

Forma y color: white xtl.

Peso molecular: 410.53

Ref: 08-15-1143

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

CAS: 657408-07-6

Fórmula: C₂₆H₃₅O₂P

Pureza: 99%

Forma y color: Solid

Peso molecular: 410.5287

Ref: IN-DA0033A9

2-(Dicyclohexylphosphanyl)-2',6'-dimethoxybiphenyl

CAS: 657408-07-6

2-(Dicyclohexylphosphanyl)-2',6'-dimethoxybiphenyl

Fórmula: C₂₆H₃₅O₂P

Pureza: 98%

Forma y color: Solid-Powder

Peso molecular: 410.52866

Ref: 54-OR40584

2-Dicyclohexylphosphino-2'',6''-dimethoxybiphenyl

CAS: 657408-07-6

Fórmula: C₂₆H₃₅O₂P

Pureza: ≥ 98.0%

Forma y color: White to off-white powder

Peso molecular: 410.54

Ref: 7W-GK5403

Dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine

CAS: 657408-07-6

Fórmula: C₂₆H₃₅O₂P

Pureza: 98.0%

Forma y color: Solid, Powder or Crysalline Powder or Solid or Chunks

Peso molecular: 410.538

Ref: 10-F078390

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

CAS: 657408-07-6

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl is a fluorescent chemical that has been used to study interactions of fatty acids and halides. It is also used in the synthesis of palladium complexes, which have been shown to be effective for hydrogenation reactions. 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl can be synthesized from 2,6-dichlorobenzaldehyde and dicyclohexylphosphine by the addition of trifluoroacetic acid. The synthesis proceeds via a substitution reaction with methoxy groups on the aromatic ring. This product fluoresces under ultraviolet light at 351 nm.

Fórmula: C₂₆H₃₅O₂P

Pureza: Min. 95%

Forma y color: Powder

Peso molecular: 410.53 g/mol

Ref: 3D-FD31495

S-Phos

Producto controlado

CAS: 657408-07-6

Applications S-Phos is a catalyst that is used in the preparation of thiadiazoles as DGAT1 inhibitors with potential in metabolic diseases treatment.
References Mougenot, P., et la.: Bioorg. Med. Chem. Lett., 22, 2497 (2012);

Fórmula: C₂₆H₃₅O₂P

Forma y color: Neat

Peso molecular: 410.53

Ref: TR-S681720

SPhos

CAS: 657408-07-6

Dicyclohexyl(2',6'-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine

Fórmula: C₂₆H₃₅O₂P

Pureza: 98%

Peso molecular: 410.53

Ref: IN-DG22053

S-Phos (2-Dicyclohexylphosphino-2,6-Dimethoxybiphenyl) extrapure, 98%

CAS: 657408-07-6

Fórmula: C₂₆H₃₅O₂P

Pureza: min.98%

Forma y color: White, Crystalline powder

Peso molecular: 410.53

Ref: SR-77061