CAS 930601-66-4

Formule : C21H35F6N3P2Ru

InChI : InChI=1S/C14H27N2P.C5H5.C2H3N.F6P.Ru/c1-10(2)17(11(3)4)13-15-12(9-16(13)8)14(5,6)7;1-2-4-5-3-1;1-2-3;1-7(2,3,4,5)6;/h9-11H,1-8H3;1-5H;1H3;;/q;;;-1;+1

Code InChI : XHAIYVPZBQIYKW-UHFFFAOYSA-N

SMILES : CC#N.CC(C)P(C1=NC(=CN1C)C(C)(C)C)C(C)C.C1=C[CH]C=C1.F[P-](F)(F)(F)(F)F.[Ru+]

(Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-κN,κP](η5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate

Produit contrôlé

CAS : 930601-66-4

Applications (Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-κN,κP](η5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate, is an Alkene Zipper Catalyst, used in selective transformation of a large variety of ω-alkenyl cyclopropylcarbinols into stereodefined unconjugated (E)-acyclic aldehydes .
References Bruffaerts, J., Vasseur, A., & Marek, I. (2018). Alkene-Zipper Catalyzed Selective and Remote Retro-ene Reaction of Alkenyl Cyclopropylcarbinol. Advanced Synthesis & Catalysis, 360(7), 1389–1396.

Formule : C₂₁H₃₅N₃PRu·PF₆

Couleur et forme : Neat

Masse moléculaire : 606.53

Ref: TR-A164155

Acetonitrile(cyclopenta­dienyl)[2-(di-i-propyl­phosphino)-4-(t-butyl)-1-methyl-1H-imidazole]ruthenium(II) hexafluorophosphate, min. 98% [Alkene Zipper Catalyst]

CAS : 930601-66-4

Acetonitrile(cyclopentadienyl)[2-(di-i-propylphosphino)-4-(t-butyl)-1-methyl-1H-imidazole]ruthenium(II) hexafluorophosphate, min. 98% [Alkene Zipper Catalyst]

Formule : C₂₁H₃₅F₆N₃P₂Ru

Degré de pureté : min. 98%

Couleur et forme : orange solid

Masse moléculaire : 606.53

Ref: 08-44-0017