CAS 498-07-7

1,6-anidro-β-D-glucosio

Descrizione:

1,6-anidro-β-D-glucosio è un derivato zuccherino ciclico caratterizzato dalla sua struttura unica, che presenta un anello a sei membri formato dalla disidratazione di due gruppi idrossilici nelle posizioni 1 e 6 del β-D-glucosio. Questo composto è un solido cristallino bianco che è solubile in acqua, riflettendo la sua natura polare a causa della presenza di gruppi idrossilici. Si trova comunemente in vari polisaccaridi naturali, in particolare nella struttura di alcuni materiali vegetali e come prodotto della degradazione della cellulosa. La forma anidra indica che manca una molecola d'acqua che sarebbe normalmente presente nella sua forma idratata, il che influisce sulla sua reattività e stabilità. 1,6-anidro-β-D-glucosio può partecipare a varie reazioni chimiche, inclusa la glicosilazione e l'ossidazione, rendendolo di interesse sia in applicazioni biochimiche che industriali. Il suo ruolo nella chimica dei carboidrati e le potenziali applicazioni in farmacologia e scienza alimentare evidenziano la sua importanza in processi sia naturali che sintetici.

Formula: C₆H₁₀O₅

InChI: InChI=1/C6H10O5/c7-3-2-1-10-6(11-2)5(9)4(3)8/h2-9H,1H2/t2-,3+,4-,5+,6-/m0/s1

InChI key: InChIKey=TWNIBLMWSKIRAT-VFUOTHLCSA-N

SMILES: O[C@@H]1[C@@]2(O[C@@](OC2)([C@H](O)[C@H]1O)[H])[H]

Sinonimi:

• 1,6-Anhydro-<span class="text-smallcaps">D</span>-glucopyranoside
• 1,6-Anhydro-<span class="text-smallcaps">D</span>-glucose
• 1,6-Anhydro-Beta-D-Glucopyranose
• 1,6-Anhydro-D-glucopyranoside
• 1,6-Anhydro-D-glucose
• 1,6-Anhydro-β-<span class="text-smallcaps">D</span>-glucopyranose
• 1,6-Anhydro-β-<span class="text-smallcaps">D</span>-glucose
• 1,6-Anhydro-β-D-glucopyranose
• 1,6-Anhydroglucose
• 1,6-anhidro-β-D-glucosa
• 6,8-Dioxabicyclo[3.2.1]octane, β-<span class="text-smallcaps">D</span>-glucopyranose deriv.
• <span class="text-smallcaps">D</span>-Glucose, 1,6-anhydro-
• D-Glucose, 1,6-anhydro-
• GLUCOPYRANOSE (,beta.-D), 1,6-ANHYDRO-
• Leucoglucosan
• Levoglucosan
• Nsc 46243
• β-<span class="text-smallcaps">D</span>-Glucopyranose, 1,6-anhydro-
• β-D-Glucopyranose, 1,6-anhydro-
• 6,8-Dioxabicyclo[3.2.1]octane, β-D-glucopyranose deriv.
• (-)-1,6-ANHYDRO-B-D-GLUCOPYRANOSE FOR SY
• 1,6-Anhydro-beta-D-glucopyranose, 99+%
• 1,6-Anhydro-β-D-glucose ,98%
• 1,6-Anhydro-?-glucopyranose
• 1,6-anhydro-á-d-glucopyranose
• 1,6-ANHYDRO-SS-D-GLUCOPYRANOSE, 99% MIN., HPLC
• 1,6-anhydro-β-d-[1-2H]glucose
• beta-D-Glucopyranose, 1,6-anhydro-
• Laevoglucosan
• 1,6-Anhydro-beta-D-glucopyranose (levoglucosan)
• 1,6-Anhydro-D-glucopyranose, 99℉
• 1,6-Anhydro-
• 1,6-Anhydro-β-D-glucose,Levoglucosan
• (-)-1,6-Anhydro--D-glucopyranose for synthesis
• 1,6-Anhydro-beta-D-glucopyranose min. 98%
• 1,6-Anhydro-β-D-glycopyranose
• 1,6-Anhydro-beta-D-glucose 99%
• 1,6-ANHYDRO-BETA-D-GLUCOSE (LEVOGLUCOSAN)
• 1,6-ANHYDRO-SS-D-GLUCOPYRANOSE
• 1,6-anhydro-beta-glucopyranose
• 1,6-ANHYDRO-BETA-D-GLUCOPYRA
• 1,6-ANHYDRO-BETA-D-GLUCOSE
• 1,6-anhydro-β-d-[UL-2H7]glucose
• 1,6-anhydro-beta-d-glucopyranos
• 1,6-anhydro-D-glucose (50 mg)
• 1,6-Dideoxy-1,6-epoxy-β-D-glucopyranose
• 1,6-Anhydro-β-glucopyranose
• 1,6-ANHYDRO-B-D-GLUCOSE

1,6-Anhydro-β-D-glucose

CAS: 498-07-7

Formula: C₆H₁₀O₅

Purezza: >99.0%(GC)

Colore e forma: White to Light yellow powder to crystal

Peso molecolare: 162.14

Ref: 3B-A1074

1,6-Anhydro-β-D-glucopyranose, 99%

CAS: 498-07-7

1,6-Anhydro-beta-D-glucopyranose is used for the preparation of biologically important and structurally diverse products such as rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, macrolide antibiotics and modified sugars. It is used as a chemical tracer for biomass burning

Formula: C₆H₁₀O₅

Purezza: 99%

Colore e forma: Powder or crystals or crystalline powder, White

Peso molecolare: 162.14

Ref: 02-A16724

1,6-anhydro-D-glucose

CAS: 498-07-7

Heterocyclic compounds with oxygen hetero-atom(s) only, nesoi

Formula: C₆H₁₀O₅

Colore e forma: White Beige Powder

Peso molecolare: 162.05282

Ref: 45-1035300

b-D-Glucopyranose, 1,6-anhydro-

CAS: 498-07-7

Formula: C₆H₁₀O₅

Purezza: 98%

Colore e forma: Solid

Peso molecolare: 162.1406

Ref: IN-DA00I8WB

1,6-Anhydro-β-D-glucopyranose

CAS: 498-07-7

1,6-Anhydro-β-D-glucopyranose

Formula: C₆H₁₀O₅

Purezza: 98%

Colore e forma: Beige Solid

Peso molecolare: 162.1406

Ref: 54-OR4810T

Levoglucosan

CAS: 498-07-7

Levoglucosan

Formula: C₆H₁₀O₅

Purezza: ≥95%

Peso molecolare: 162.14

Ref: 54-BUP18060

Levoglucosan

Prodotto controllato

CAS: 498-07-7

Formula: C₆H₁₀O₅

Colore e forma: Neat

Peso molecolare: 162.14

Ref: 04-C14629735

Levoglucosan (Standard)

CAS: 498-07-7

Levoglucosan (Standard) is the standard substance of Levoglucosan, and it is applicable for quantitative analysis, quality control, and related research in biochemical experiments. Levoglucosan (1,6-anhydro-b-D-Glucose) is an anhydrohexose that is the 1,6-anhydro-derivative of beta-D-glucopyranose. It is formed from the pyrolysis of carbohydrates, such as starch and cellulose. Levoglucosan can also be utilized in the synthesis of chiral polymers such as unhydrolysable glucose polymers. Levoglucosan is also produced via caramelization of sugar. Consumption of caramel or caramel-containing sweets can lead to a short-term 5X increase in urinary levels of levoglucosan (from 20 uM/mM creatinine to 100 uM/mM creatinine).

Formula: C₆H₁₀O₅

Colore e forma: Solid

Peso molecolare: 162.14

Ref: TM-TMSM-1457

Levoglucosan

CAS: 498-07-7

Levoglucosan is a byproduct of carbohydrate pyrolysis, used in chiral polymer synthesis, and increases in urine post-caramel consumption.

Formula: C₆H₁₀O₅

Purezza: 99.92% - ≥95%

Colore e forma: Solid

Peso molecolare: 162.14

Ref: TM-T5250

1,6-Anhydro-β-D-glucopyranose

CAS: 498-07-7

1,6-Anhydro-β-D-glucopyranose

Formula: C₆H₁₀O₅

Purezza: 98%

Colore e forma: Solid-Powder

Peso molecolare: 162.1406

Ref: 54-BICL4018

1,6-Anhydro-β-D-glucopyranose

CAS: 498-07-7

Formula: C₆H₁₀O₅

Purezza: (HPLC) ≥ 99.0%

Colore e forma: White crystalline powder

Peso molecolare: 162.14

Ref: 7W-GC5907

1,6-Anhydro-β-D-glucopyranose

CAS: 498-07-7

Stability Hygroscopic
Applications 1,6-Anhydrohexopyranoses have proven to be valuable synthons for the preparation of biologically important and structurally diverse products (e.g. rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, and macrolide antibiotics) as well as for modified sugars.The chemical/physical/toxicological properties have not been thoroughly investigated. Since it is known to be a minor component of certain food materials it may be regarded as of relatively low toxicity.
References Fraser-Reid, B., et al. J. Am. Chem. Soc. 106, 731 (1984); Edwards, M.P., et al. J. Org. Chem. 49, 3503 (1984); Kelly, A.G., and Roberts, J.S. J. Chem. Soc., Chem. Commun. 228, (1980); Ogawa, T., et al. Carbohydr. Res. 57, C31 (1977); Isobe, M., et al. Tetrahedron Lett. 28, 6485 (1987); Fresnos, J.N. and Swenton, J.S. , J. Chem. Soc., Chem. Commun. 658, (1985); Kochetkov, N.K. et al., Tetrahedron Lett. 22, 4315, 4319 (1981); Georges, M. et al., Carbohydr. Res. 130, 115 (1984); Paulsen, et al., Chem. Ber. 114, 322 (1981).

Formula: C₆H₁₀O₅

Colore e forma: Neat

Peso molecolare: 162.14

Ref: TR-A648100

1,6-Anhydro-beta-D-glucopyranose

CAS: 498-07-7

Used for preparation of biologically active compounds

Formula: C₆H₁₀O₅

Purezza: Min. 98 Area-%

Colore e forma: White Powder

Peso molecolare: 162.14 g/mol

Ref: 3D-ML06636

1,6-Anhydro-β-d-glucose

CAS: 498-07-7

Formula: C₆H₁₀O₅

Purezza: 95%

Colore e forma: Solid, Light beige powder

Peso molecolare: 162.053

Ref: 10-F046709