Trichloro[2-(chloromethyl)-2-propen-1-yl]silane

CAS: 18147-84-7

Rif. TR-T294870

Informazioni sul prodotto

• Nome: Trichloro[2-(chloromethyl)-2-propen-1-yl]silane
• Sinonimi: trichloro-[2-(chloromethyl)prop-2-enyl]silane, Trichloro(2-(Chloromethyl)Allyl)Silane, Trichloro[2-(Chloromethyl)Prop-2-En-1-Yl]Silane

Descrizione

Applications Trichloro[2-(chloromethyl)-2-propen-1-yl]silane is an intermediate used in the synthesis of 2-​(Chloromethyl)​allyl-​trimethylsilane (C371430), which is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-​(Chloromethyl)​allyl-​trimethylsilane was used in catalytic Sakurai reaction of α,​β-​enones.
References Kopecky, D., et al.: J. Am. Chem. Soc., 123, 8420 (2001).Lee, P., et al.: J. Org. Chem., 66, 8646 (2001).

• Marchio: TRC

Proprietà chimiche

• Peso molecolare: 223.988
• Formula: C₄H₆Cl₄Si
• Colore/Forma: Neat
• InChI: InChI=1S/C4H6Cl4Si/c1-4(2-5)3-9(6,7)8/h1-3H2
• InChI key: InChIKey=SJFJNNLIAXEOSE-UHFFFAOYSA-N
• SMILES: C=C(CCl)C[Si](Cl)(Cl)Cl