CAS 12354-84-6

Irídio, di-μ-clorodiclorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentametil-2,4-ciclopentadien-1-il]di-

Descrição:

Irídio, di-μ-clorodiclorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentametil-2,4-ciclopentadien-1-il]di- é um composto organometálico complexo que apresenta irídio como o átomo central de metal. Este composto é caracterizado por sua coordenação com múltiplos ligantes, especificamente cloretos e derivados de ciclopentadieno, que contribuem para suas propriedades estruturais e eletrônicas únicas. A presença dos substituintes pentametila nos anéis de ciclopentadieno melhora a estabilidade e solubilidade do complexo. Os complexos de irídio são conhecidos por suas propriedades catalíticas, particularmente na síntese orgânica e no campo da ciência dos materiais. A ponte di-μ-cloro indica que os cloretos estão atuando como ligantes de ponte entre os centros de irídio, o que pode influenciar a reatividade e o ambiente de coordenação do metal. No geral, este composto exemplifica a intrincada interação entre metal e ligante que define o comportamento dos complexos de metais de transição em várias aplicações químicas.

Fórmula: C₂₀H₃₀Cl₄Ir₂

InChI: InChI=1S/2C10H15.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q2*-1;;;;;2*+3/p-4

Chave InChI: InChIKey=MMAGMBCAIFVRGJ-UHFFFAOYSA-J

SMILES: [Cl-][Ir+3]12345(C=6(C)C1(C)=C2(C)[C-]3(C)C46C)[Cl-][Ir+3]789%10([Cl-])([Cl-]5)[C-]%11(C)C7(C)=C8(C)C9(C)=C%10%11C

Sinónimos:

• (Ir(Cp*)Cl₂)₂
• (Pentamethylcyclopentadienyl)iridium dichloride dimer
• (Pentamethylcyclopentadienyl)iridium(III)Dichloride Dimer
• (η⁵-Pentamethylcyclopentadienyl)iridium dichloride dimer
• 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, iridium complex
• Bis((μ-chloro)chloro(η⁵-pentamethylcyclopentadienyl)iridium)
• Bis(chloro(μ₂-chloro)(η⁵-pentamethylcyclopentadienyl)iridium)
• Bis(dichloro(η⁵-pentamethylcyclopentadienyl)iridium)
• Bis(dichloro(η⁵-η-pentamethylcyclopentadienyl)iridium)
• Bis(pentamethylcyclopentadiene)tetrachlorodiiridium
• Bis(pentamethylcyclopentadienyliridium dichloride)
• Bis(μ-chloro)bis[chloro(η⁵-pentamethylcyclopentadienyl)iridium]
• Bis[dichloro(pentamethylcyclopentadienyl)iridium]
• Di-μ-chlorobis(chloro(η⁵-pentamethylcyclopentadienyl)iridium)
• Di-μ-chlorodichlorobis(pentamethylcyclopentadienyl)diiridium
• Dichloro(pentamethylcyclopentadienyl)iridium dimer
• Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
• Dichlorobis(μ₂-chloro)bis(η⁵-pentamethylcyclopentadienyl)diiridium
• Dichlorodi-μ-chlorobis(η⁵-pentamethylcyclopentadienyl)diiridium
• Dichloropentamethylcyclopentadienyliridiumdimer
• Iridium, di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
• Pentamethylcyclopentadienyl)iridium(III) chloride dimer
• Pentamethylcyclopentadienyliridium(III) chloride,dimer
• Pentamethylcyclopentadienyliridium(III) dichloride dimer
• Tetrachlorobis(pentamethylcyclopentadienyl)diiridium
• Tetrachlorobis(η⁵-pentamethylcyclopentadienyl)diiridium

(Pentamethylcyclopentadienyl)iridium(III) Dichloride Dimer

CAS: 12354-84-6

Fórmula: C₂₀H₃₀Cl₄Ir₂

Pureza: >95.0%(T)

Cor e Forma: Light yellow to Brown powder to crystal

Peso molecular: 796.69

Ref: 3B-P1763

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer

CAS: 12354-84-6

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is used as a precursor to catalysts for the asymmetric transfer hydrogenation of ketones. It is a catalyst for greener amine synthesis. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some

Fórmula: C₂₀H₃₀Cl₄Ir₂

Cor e Forma: Orange, Crystals or crystalline powder

Peso molecular: 796.69

Ref: 02-045565

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer, 98%

CAS: 12354-84-6

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer, 98%

Fórmula: (CH₃)₅C₅IrCl₂

Pureza: 98%

Cor e Forma: orange xtl.

Peso molecular: 796.67

Ref: 08-77-1060

Iridium,di-m-chlorodichlorobis[(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-

CAS: 12354-84-6

Fórmula: C₂₀H₃₀Cl₄Ir₂

Pureza: 98%

Cor e Forma: Solid

Peso molecular: 796.6982

Ref: IN-DA00HHBN

(Pentamethylcyclopentadienyl)iridium(III) dichloride dimer

CAS: 12354-84-6

(Pentamethylcyclopentadienyl)iridium(III) dichloride dimer

Fórmula: C₂₀H₃₀Cl₄Ir₂

Pureza: 98%,Ir:48%,high pure

Cor e Forma: orange powder

Peso molecular: 796.70g/mol

Ref: 54-OR49087

Pentamethylcyclopentadienyliridium(III) chloride, dimer

CAS: 12354-84-6

Fórmula: C₂₀H₃₀Cl₄Ir₂

Pureza: ≥ 97.0%

Cor e Forma: Yellow to orange powder

Peso molecular: 796.70

Ref: 7W-GX6497

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer

Produto Controlado

CAS: 12354-84-6

Applications Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is commonly found to be used as a catalyst in reactions, and the synthesis oxidative arylation with indoles, azobenzene derivatives., and ortho-​alkynylated arylalkylamines.
References Li, G., et al.: Org. Lett., 20, 2454-58 (2018); Tindall, D.J., et al.: J. Am. Chem. Soc., 140, 1884-93 (2018); Chen, X., et al.: Org. Lett., 20, 1171-74 (2018);

Fórmula: C₂₀H₃₀Cl₄Ir₂

Cor e Forma: Neat

Peso molecular: 796.7

Ref: TR-D438770

DICHLORO(PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM(III) DIMER

CAS: 12354-84-6

Fórmula: C₂₀H₃₀Cl₄Ir₂

Pureza: 98%

Peso molecular: 796.69

Ref: 10-F053213

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer

CAS: 12354-84-6

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer (DCPI) is a synthetic ligand that can be used in biomolecular and chemical applications. DCPI has been shown to be stable in the presence of chloride, which is needed for many catalytic reactions. This compound has high activity as a transfer agent and is also able to transfer amines and cyclic compounds. DCPI can be used in fluorescence-based assays, due to its strong fluorescence emission.

Fórmula: C₂₀H₃₀Cl₄Ir₂

Pureza: Min. 95%

Cor e Forma: Powder

Peso molecular: 796.7 g/mol

Ref: 3D-FD55182