CAS 138124-32-0

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTILSALICILIDENO)-1,2-CICLOHEXANODIAMINO-MANGANÊS(III) CLORIDO

Descrição:

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTILSALICILIDENO)-1,2-CICLOHEXANODIAMINO-MANGANÊS(III) CLORIDO é um composto de coordenação que apresenta um centro de manganês coordenado a um ligando bidentado derivado de uma diamina quiral e derivados de salicilaldeído. Este composto é caracterizado por sua significativa hindrance estérica devido à presença de grupos tert-butilo volumosos nas moieties salicilidênicas, que podem influenciar sua reatividade e seletividade em processos catalíticos. O estado de oxidação de manganês(III) é notável por sua capacidade de participar em reações redox, tornando este composto de interesse em catálise e ciência dos materiais. A quiralidade do ligando confere potencial enantiosseletividade em reações, o que é valioso na síntese assimétrica. Além disso, o íon cloreto atua como um contra-íon, estabilizando o complexo. Suas características estruturais e propriedades únicas fazem dele um objeto de estudo em química de coordenação e suas aplicações em catálise, particularmente em transformações orgânicas.

Fórmula: C₃₆H₅₂ClMnN₂O₂

InChI: InChI=1/C36H54N2O2.3ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;;;/h17-22,29-30,39-40H,13-16H2,1-12H3;3*1H;/q;;;;+3/p-3/b37-21+,38-22+;;;;/t29-,30-;;;;/m0..../s1

Chave InChI: InChIKey=LJVAWOSDJSQANR-SEILFYAJSA-K

SMILES: [Cl-][Mn+3]123[N]([C@]4([C@]([N]1=CC=5C([O-]2)=C(C(C)(C)C)C=C(C(C)(C)C)C5)(CCCC4)[H])[H])=CC=6C([O-]3)=C(C(C)(C)C)C=C(C(C)(C)C)C6

Sinónimos:

• (+)-Bis(3,5-Di-T-Bu-Salicyl.)-1,2-Cyclo-Hexanediamino-Mn Cl
• (-)-Bis(3,5-Di-T-Bu-Salicyl.)-1,2-Cyclo-
• (-)-Chloro{(1R,2R)-4,4′,6,6′-tetra-tert-butyl-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}manganese(III)
• (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-BIS(3,5-DI-T-Butylsalicylidene)]MANGANESE(III)CHLORIDE
• (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-BIS(3,5-DI-T-Butylsalicylidene)]manganese (III) chloride
• (R,R)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-diaminocyclohexylmanganese(III) chloride
• (R,R)-(-)-N,N'-BIS(3.5-DI-T-Butylsalicylidene)-1,2-CYCLOHEXANEDIAMINE-manganese (III) chloride
• (R,R)-(-)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino manganese(II) chloride
• (R,R)-Jacobsen Cat.
• (R,R)-Jacobsen Catalyst
• (R,R)-Jacobsen'S Catalyst
• (R,R)-Jacobsen'S Catalyst Manganese(Iii) Chloride Complex
• (R,R)-[N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride
• (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-Butylsalicylidene)-1,2-Cyclohexanediamino-MANGANESE(III) CHLORIDE
• (S,S)-Jacobsen Cat.
• (S,S)-Jacobsen Catalyst
• (S,S)-Jacobsen'S Catalyst
• (S,S)-Jacobsen'S Catalyst Manganese(Iii) Chloride Complex
• (S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL-IDENE)-1,2-Cyclohexanediamino-MN-CL
• (SP-5-13)-Chloro[[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]manganese
• 2,2'-{(1R,2R)-cyclohexane-1,2-diylbis[nitrilo(E)methylylidene]}bis(4,6-di-tert-butylphenol)-trichloromanganese (1:1)
• 2,2'-{(1S,2S)-cyclohexane-1,2-diylbis[nitrilo(E)methylylidene]}bis(4,6-di-tert-butylphenol)-trichloromanganese (1:1)
• Jacobsen'S Catalyst
• Manganese, chloro[[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]-, (SP-5-13)-
• Manganese, chloro[[2,2′-[1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)phenolato]](2-)-N,N′,O,O′]-, [SP-5-13-(1R-trans)]-
• Manganese, chloro[[2,2′-[1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]-, [SP-5-13-(1R-trans)]-
• chloro[[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]manganese
• -N,N'-Bis(3,5-di-tertbutylsalicylidene)
• (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
• (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminemanganese(III)chloride
• (R,R)-(-)-[N,N(1)-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaMinoat(2-)]Manganese(III) chloride
• (R,R)Jacobesn
• (R,R)(-)N,N'Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco
• (R,R)-Jacobsen’s catalyst, Jacobsen’s catalyst
• (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III)chloride,98%(R,R)-JacobsenCat.
• Jacobsen
• Jacobsen'scatalyst(R,R)
• 96+%(chn)
• (R,R)-form
• (1R,2R)-(-)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese (III) chloride (R,R)-Jacobsen Cat.
• -1,2- cyclohexanediaminomanganese(III)
• (R,R)-N,N -BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL
• (R,R)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL98%

(1R,2R)-(-)-[1,2-Cyclo­hexanediamino-N,N'-bis(3,5-di-t-butyl­salicylidene)]manganese (III) chloride, 98% (R,R)-Jacobsen Cat.

CAS: 138124-32-0

(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese (III) chloride, 98% (R,R)-Jacobsen Cat.

Fórmula: C₃₆H₅₂ClMnN₂O₂

Pureza: 98%

Cor e Forma: brown pwdr.

Peso molecular: 635.22

Ref: 08-25-0300

(R,R)-Jacobsen's catalyst

CAS: 138124-32-0

Fórmula: C₃₆H₅₂ClMnN₂O₂

Pureza: 97%

Cor e Forma: Solid

Peso molecular: 635.2013

Ref: IN-DA003CCA

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride

CAS: 138124-32-0

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride

Pureza: 98%,99%ee

Peso molecular: 635.21g/mol

Ref: 54-OR72454

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride

CAS: 138124-32-0

Fórmula: C₃₆H₅₂ClMnN₂O₂

Pureza: >98.0%(HPLC)

Cor e Forma: Orange to Brown powder to crystal

Peso molecular: 635.21

Ref: 3B-B5613

(R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

CAS: 138124-32-0

(R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is a diamine ligand that has been used for the immobilization of ethylene. The reaction proceeds via an oxidation catalyzed by a metal such as copper or manganese. The reaction products are chlorides and alcohols. The molecular modeling and x-ray crystal structures of these reactions have been studied and kinetic data have been collected. Kinetics measurements show that the reactions are fast with an activation energy of 45 kcal/mol and proceed through a hydrogen transfer mechanism.

Fórmula: C₃₆H₅₂ClMnN₂O₂

Pureza: Min. 95%

Cor e Forma: Powder

Peso molecular: 635.2 g/mol

Ref: 3D-FB30906

(R,R)-(-)-N,N’-Bis(3,5-di-tertbutylsalicylidene)-1,2- cyclohexanediaminomanganese(III) chloride

CAS: 138124-32-0

Pureza: 97%

Peso molecular: 634.31

Ref: 10-F552090