CAS 14647-23-5

(Bis(difenilfosfino)etano)dicloro níquel

Descrição:

(Bis(difenilfosfino)etano)dicloro níquel, comumente referido como NiCl2(dppeth), é um composto de coordenação que apresenta níquel em um estado de oxidação +2 coordenado a dois ligandos de difenilfosfinoetano e dois íons cloreto. Este composto normalmente exibe uma geometria quadrada plana devido à configuração eletrônica d8 do níquel, que é característica de muitos complexos de níquel(II). Os ligandos de difenilfosfinoetano contribuem para a estabilidade e solubilidade geral do complexo em solventes orgânicos. NiCl2(dppeth) é frequentemente utilizado em catálise, particularmente em reações de acoplamento cruzado e outras transformações orgânicas, devido à sua capacidade de facilitar a transferência de elétrons e promover a formação de ligações. A presença de átomos doadores de fósforo aumenta a reatividade do centro de níquel, tornando-o um composto importante na química organometálica. Além disso, o composto pode exibir propriedades térmicas e fotocatalíticas interessantes, que podem ser relevantes em várias aplicações, incluindo ciência dos materiais e catálise.

Fórmula: C₂₆H₂₄Cl₂NiP₂

InChI: InChI=1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

Chave InChI: InChIKey=XXECWTBMGGXMKP-UHFFFAOYSA-L

SMILES: [Cl-][Ni+2]1([Cl-])[P](CC[P]1(C2=CC=CC=C2)C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5

Sinónimos:

• (Bis(diphenylphosphino)ethane)dichloronickel
• 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
• 1,2-Bis(diphenylphosphino)ethanedichloronickel
• 1,2-Bis(diphenylphosphino)ethanenickel dichloride
• 1,2-Ethylenebis(diphenylphosphine)nickel dichloride
• DPPE.NiCl2
• Dichloro-1,2-bis(diphenylphosphino)ethanenickel(II)
• Dichloro[1,2-bis(diphenylphosphino)ethane]nickel
• Dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II)
• Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P′]nickel
• Dichloro[1,2-ethanediylbis[diphenylphosphine]]nickel
• Dichloro[ethylenebis[diphenylphosphine]]nickel
• Dichlorobis[(diphenylphosphino)ethane]nickel(II)
• Nickel 1,2-Bis(diphenylphosphino)ethane dichloride
• Nickel, dichloro[1,2-ethanediylbis[diphenylphosphine-κP]]-, (SP-4-2)-
• Nickel, dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P′]-, (SP-4-2)-
• Nickel, dichloro[ethylenebis[diphenylphosphine]]-
• Nickel, dichloro[ethylenebis[diphenylphosphine]]-, cis-
• Phosphine, 1,2-ethanediylbis[diphenyl-, nickel complex
• [1,2-Bis(Diphenylphosphino)Ethane]Dichloronickel(Ii)
• [1,2-Bis(diphenylphosphino)ethane]dichloronickel

[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride

CAS: 14647-23-5

Fórmula: C₂₆H₂₄Cl₂NiP₂

Pureza: >96.0%(T)

Cor e Forma: Orange to Amber to Dark red powder to crystal

Peso molecular: 528.02

Ref: 3B-B2225

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98%

CAS: 14647-23-5

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols

Fórmula: C₂₆H₂₄Cl₂NiP₂

Pureza: 98%

Cor e Forma: Orange-red to brown, Powder

Peso molecular: 528.02

Ref: 02-013932

1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride

CAS: 14647-23-5

Fórmula: C₂₆H₂₄Cl₂NiP₂

Pureza: 98%

Cor e Forma: Solid

Peso molecular: 528.0157

Ref: IN-DA0032KC

1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride

CAS: 14647-23-5

1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride

Pureza: 98%

Peso molecular: 528.02g/mol

Ref: 54-IN10319

[Bis(diphenylphosphino)ethane]dichloronickel

Produto Controlado

CAS: 14647-23-5

Applications [Bis(diphenylphosphino)ethane]dichloronickel is a coordination complex with potential antitumor activity. It is also used as a fast and efficient hydrogen production catalyst.
References Mirabelli, C.K., et al.: J. Med. Chem., 30, 2181 (1987); Gan, L., et al.: J. Am. Chem. Soc., 137, 1109 (2015)

Fórmula: C₂₆H₂₄Cl₂NiP₂

Cor e Forma: Neat

Peso molecular: 528.02

Ref: TR-B430455

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

CAS: 14647-23-5

Fórmula: C₂₆H₂₄Cl₂NiP₂

Pureza: 96%

Cor e Forma: Solid, Yellow red - deep yellow red powder

Peso molecular: 526.008

Ref: 10-F077791

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride, 99%

CAS: 14647-23-5

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride, 99%

Fórmula: (C₆H₅)₂PCH₂CH₂P(C₆H₅)₂NiCl₂

Pureza: 99%

Cor e Forma: orange xtl.

Peso molecular: 528.04

Ref: 08-28-0030

[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride

CAS: 14647-23-5

Bis-diphenylphosphinoethane nickel dichloride is a compound that is used for the preparation of other compounds, such as phosphine ligands. Bis-diphenylphosphinoethane nickel dichloride is a solid form of nickel chloride with two crystalline polymorphs, one with a monoclinic crystal structure and the other with a tetragonal crystal structure. In order to obtain the desired product, it must be prepared in an orientational process and synthesised at low temperatures. Bis-diphenylphosphinoethane nickel dichloride has been shown to have anti-cancer properties.br>br> Bis-diphenylphosphinoethane nickel dichloride has also been used to prepare other compounds by cross coupling reactions. This method is effective for preparing compounds that are difficult to make using conventional methods, such as organometallic complexes.br>br> Bis-d

Fórmula: C₂₆H₂₄Cl₂NiP₂

Pureza: Min. 95%

Peso molecular: 528.02 g/mol

Ref: 3D-FB60935