CAS 15629-92-2

Dicloro[1,1′-(1,3-propanodienil)bis[1,1-difenilfosfina-κP]]níquel

Descrição:

Dicloro[1,1′-(1,3-propanodienil)bis[1,1-difenilfosfina-κP]]níquel, com o número CAS 15629-92-2, é um composto de coordenação que apresenta um centro de níquel coordenado a dois ligantes de difenilfosfina e dois íons cloreto. Este composto é caracterizado por seus ligantes de fosfina bidentados, que aumentam sua estabilidade e reatividade. A presença do conector 1,3-propanodilo fornece uma estrutura única que influencia o arranjo espacial dos ligantes ao redor do átomo de níquel. Tipicamente, complexos de níquel como este exibem uma geometria quadrada plana, que é comum para complexos de níquel(II). Os ligantes de difenilfosfina contribuem para as propriedades eletrônicas do complexo, potencialmente tornando-o útil em catálise e síntese orgânica. Além disso, a solubilidade e reatividade do composto podem variar dependendo do solvente e das condições, tornando-o um assunto de interesse em química de coordenação e ciência dos materiais. Precauções de segurança devem ser tomadas ao manusear este composto, pois pode apresentar riscos à saúde típicos de compostos organofosforados.

Fórmula: C₂₇H₂₆Cl₂NiP₂

InChI: InChI=1/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2

Chave InChI: InChIKey=ZBQUMMFUJLOTQC-UHFFFAOYSA-L

SMILES: [Cl-][Ni+2]1([Cl-])[P](CCC[P]1(C2=CC=CC=C2)C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5

Sinónimos:

• 1,3-Bis(diphenylphosphino)nickel dichloride
• 1,3-Bis(diphenylphosphino)propane dichloronickel
• 1,3-Bis(diphenylphosphino)propane nickel chloride
• 1,3-Bis(diphenylphosphino)propanenickel dichloride
• Bis[1,3-bis(diphenylphosphino)propane]dichloronickel
• DPPP.NiCl2
• Dichloro[1,1′-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]nickel
• Dichloro[1,3-Bis-(diphenylphosphino)propane] nickel(Ⅱ)
• Dichloro[1,3-bis(diphenylphosphino)propane]nickel
• Dichloronickel-Propane-1,3-Diylbis(Diphenylphosphane) (1:1)
• Nickel 1,3-bis(diphenylphosphino)propane dichloride
• Nickel, dichloro[1,1′-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]-
• Nickel, dichloro[1,3-propanediylbis[diphenylphosphine-κP]]-
• Nickel, dichloro[1,3-propanediylbis[diphenylphosphine]-P,P′]-
• Nickel, dichloro[trimethylenebis[diphenylphosphine]]-
• Phosphine, 1,3-propanediylbis[diphenyl-, nickel complex
• [1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
• [1,3-Bis(diphenylphosphino)propane]nickel(II)Dichloride
• [Bis(diphenylphosphino)propane]nickel dichloride
• 1,3-Bis(diphenylphosphino)propane nickel(II) chloride
• 1,3-Bis(Diphenylphosphino)Propane nickel(II)Chloride
• 1,3-bis(diphenylphosphino)propane nickel ii chloride
• 1,3-BIS(DIPHENYLPHOSPHINE)PROPANE NICKEL(II) CHLORIDE
• NiCl2(DPPP)NiCl2(DPPP)
• Dichloro[1,3-Bis-(Diphenylphos
• NICL2(DPPP)/ 1,3-BIS(DIPHENY PHOSPHINE) PROPANE NICKEL(II)CHLORIDE
• DICHLORO[1,3-BIS-(DIPHENYLPHOSPHINO)PROPANE] NICKE
• 1,3-Bis(dipenylphosphino)propanenickel(II) chloride
• 1,3-Bis(diphenyl phosphine)propane nickel(II)dichloride
• Dichlorobis(1,3-diphenylphosphino)propaneünickel(II), C 59.9%
• 1,3-BIS-(DIPHENYLPHOSPHINO)-PROPAN-
• 1,3-Bis(diphenylphosphino)propanenickel(II)chloride,99%
• 1.3-Bis(dipheny phosphine) propane nickel(II)chloride
• (1,3-dppp)NiCl2, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride

[1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride

CAS: 15629-92-2

Fórmula: C₂₇H₂₆Cl₂NiP₂

Pureza: >98.0%(T)

Cor e Forma: Orange to Brown to Dark red powder to crystal

Peso molecular: 542.05

Ref: 3B-B1313

Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II)

CAS: 15629-92-2

Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythi

Fórmula: C₂₇H₂₆Cl₂NiP₂

Cor e Forma: Orange to red, powder

Peso molecular: 542.04

Ref: 02-030167

1,3-Bis(diphenylphosphino)propane nickel(II) chloride, 99%

CAS: 15629-92-2

1,3-Bis(diphenylphosphino)propane nickel(II) chloride, 99%

Fórmula: (C₆H₅)₂PCH₂CH₂CH₂P(C₆H₅)₂NiCl₂

Pureza: 99%

Cor e Forma: red xtl.

Peso molecular: 542.08

Ref: 08-28-0080

1,3-Bis(diphenylphosphino)propane nickel(II)chloride

CAS: 15629-92-2

Fórmula: C₂₇H₂₆Cl₂NiP₂

Pureza: 98%

Cor e Forma: Solid

Peso molecular: 542.0423

Ref: IN-DA0032I0

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

CAS: 15629-92-2

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

Fórmula: Cl₂Ni·C₂₇H₂₆P₂

Pureza: 98%

Cor e Forma: red solid

Peso molecular: 542.04g/mol

Ref: 54-OR70169

1,3-Bis(diphenylphosphino)propane-nickel (II) chloride

CAS: 15629-92-2

Fórmula: C₂₇H₂₆Cl₂NiP₂

Peso molecular: 542.03

Ref: 7W-GK3219

1,3-Bis(diphenylphosphino)propanedichloronickel II

CAS: 15629-92-2

Fórmula: C₂₇H₂₆Cl₂NiP₂

Pureza: 95%

Cor e Forma: Solid

Peso molecular: 540.024

Ref: 10-F044623

[1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride

Produto Controlado

CAS: 15629-92-2

Applications [1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins.
References Li, J., et al.: J. Polym. Res., 19, 1-9 (2012); Yamamoto, T., et al.: Tetrahedron Lett., 42, 8653-8656 (2001);

Fórmula: C₂₇H₂₆Cl₂NiP₂

Cor e Forma: Neat

Peso molecular: 542.04

Ref: TR-B430353