CAS 35138-22-8

Ródio(1+), bis[(1,2,5,6-η)-1,5-ciclooctadieno]-, tetrafluoroborato(1-) (1:1)

Descrição:

Ródio(1+), bis[(1,2,5,6-η)-1,5-ciclooctadieno]-, tetrafluoroborato(1-) é um composto de coordenação que apresenta ródio em um estado de oxidação +1, complexo com duas moléculas de ciclooctadieno, que é um dieno que pode se coordenar a metais de forma η^4. O ânion tetrafluoroborato atua como um contra-íon, proporcionando estabilidade ao complexo. Este composto é caracterizado por sua geometria única e propriedades eletrônicas, que surgem da interação entre o centro de ródio e os ligantes de ciclooctadieno. A presença do íon tetrafluoroborato contribui para sua solubilidade em solventes polares. Os complexos de ródio são frequentemente estudados por suas propriedades catalíticas, particularmente em síntese orgânica e reações de hidrogenação. A estrutura específica deste composto permite padrões de reatividade interessantes e aplicações potenciais em catálise. Além disso, a estabilidade e reatividade do composto podem ser influenciadas por fatores como temperatura, solvente e a presença de outros ligantes ou substratos. No geral, este composto exemplifica a rica química associada aos complexos de metais de transição.

Fórmula: C₁₆H₂₄Rh·BF₄

InChI: InChI=1S/2C8H12.BF4.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h2*1-2,7-8H,3-6H2;;/q;;-1;+1

Chave InChI: InChIKey=NBGSCPNNKGVTKU-UHFFFAOYSA-N

SMILES: [Rh+]123456([CH]7=[CH]1CC[CH]2=[CH]3CC7)[CH]8=[CH]4CC[CH]5=[CH]6CC8.[B+3]([F-])([F-])([F-])[F-]

Sinónimos:

• (1Z,5Z)-cycloocta-1,5-diene
• 1,5-Cyclooctadiene, rhodium complex
• Bis(1,5-Cyclooctadien)Rhodium(I) Tetrafluoroborate
• Bis(1,5-Cyclooctadiene)Rhodium Tetrafluoroborate
• Bis(1,5-cyclooctadiene)(tetrafluoroborato)rhodium
• Bis(1,5-cyclooctadiene)rhodium(1+) tetrafluoroborate
• Bis(1,5-cyclooctadiene)rhodium(1+) tetrafluoroborate(1-)
• Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate Also available as trifluoromethanesulfonate and hexafluorophosphate
• Bis(1,5-cyclooctadienyl)rhodium tetrafluoroborate
• Bis(Cycloocta-1,5-Dien)Rhodium(I)-Tetrafluoroborate
• Bis(cis,cis-1,5-cyclooctadiene)rhodium tetrafluoroborate
• Bis(cyclooctadiene)rhodium tetrafluoroborate
• Bis(cyclooctadiene)rhodium(1+) tetrafluoroborate
• Bis(cyclooctadiene)rhodium(1+) tetrafluoroborate(1-)
• Bis[(1,2,5,6-η)-1,5-cyclooctadiene]rhodium tetrafluoroborate(1-)-
• Bis[(1,2,5,6-η)-1,5-cyclooctadiene]rhodium(1+) tetrafluoroborate(1-)
• Borate(1-), tetrafluoro-, bis[(1,2,5,6-η)-1,5-cyclooctadiene]rhodium(1+)
• Dicyclooctadienerhodium tetrafluoroborate
• Rh(COD)₂BF₄
• Rhodium(+1) Cation
• Rhodium(1+), bis(1,5-cyclooctadiene)-, tetrafluoroborate(1-)
• Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, tetrafluoroborate(1-)
• Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, tetrafluoroborate(1-) (1:1)
• Rhodium(I) Tetrafluoroborate 1,5-Cyclooctadiene Complex
• Tetrafluoroborate
• Bis(1,5-Cyclooctadiene) Rhodium(I) Tetrafluoroborate
• Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate
• Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,98+%

Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate

CAS: 35138-22-8

Fórmula: C₁₆H₂₄BF₄Rh

Cor e Forma: Orange to Amber to Dark red powder to crystal

Peso molecular: 406.08

Ref: 3B-B3961

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

CAS: 35138-22-8

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an impo

Fórmula: C₁₆H₂₄BF₄Rh

Peso molecular: 406.08

Ref: 02-044031

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+%

CAS: 35138-22-8

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+%

Fórmula: Rh(C₈H₁₂)₂BF₄

Pureza: 98+%

Cor e Forma: red-brown solid

Peso molecular: 406.07

Ref: 08-45-0109

Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate

CAS: 35138-22-8

Fórmula: Rh(C₈H₁₂)₂BF₄

Cor e Forma: Red to brown solid

Peso molecular: 406.08

Ref: 7W-GX7635

Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate

CAS: 35138-22-8

Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate

Pureza: 95%

Cor e Forma: Powder

Peso molecular: 406.07g/mol

Ref: 54-PC2198

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

CAS: 35138-22-8

Fórmula: C₁₆H₂₄BF₄Rh

Pureza: 97%

Cor e Forma: Solid, No data available.

Peso molecular: 406.08

Ref: 10-F544833

Bis (1,5-Cyclooctadiene) rhodium(I)tetrafluoroborate

CAS: 35138-22-8

Bis (1,5-Cyclooctadiene) rhodium(I)tetrafluoroborate (BODIPY) is a catalyst that enhances the rate of hydrosilylation reactions. This catalyst has been shown to be effective in the synthesis of aryl chlorides from amines and aldehydes with high enantioselectivity. BODIPY is also immobilized on silica gel to create an active catalyst for asymmetric synthesis. The immobilization process on silica gel is done by reacting BODIPY with ammonium formate and amines. The resulting catalyst can be used for the synthesis of functionalized organic compounds, such as pyrrolidines, tetrahydrofurans, and thiophenes.

Fórmula: C₁₆H₂₄BF₄Rh

Pureza: Min. 95%

Peso molecular: 406.07 g/mol

Ref: 3D-FB45672

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

CAS: 35138-22-8

Fórmula: C₁₆H₂₄BF₄Rh

Pureza: 98%

Cor e Forma: Solid

Peso molecular: 406.0719

Ref: IN-DA00396S