CAS 657408-07-6

2-Diciclohexilfosfino-2',6'-dimetoxibifenil

Descrição:

2-Diciclohexilfosfino-2',6'-dimetoxibifenil é um ligante de fosfina comumente utilizado em química organometálica e catálise, particularmente em complexos de metais de transição. Este composto apresenta uma estrutura de bifenila com substituintes metóxi nas posições 2 e 6, melhorando sua solubilidade e propriedades estéricas. O grupo dicyclohexilfosfino fornece características de doador fortes, tornando-o eficaz na estabilização de centros metálicos em reações catalíticas. A presença de grupos ciclopentilo volumosos contribui para seu impedimento estérico, o que pode influenciar a seletividade e reatividade dos complexos metálicos. Este ligante é frequentemente empregado em reações de acoplamento cruzado, como as reações de Suzuki ou Heck, devido à sua capacidade de facilitar a formação de ligações carbono-carbono. Além disso, suas características estruturais únicas permitem a sintonização das propriedades eletrônicas, tornando-o uma ferramenta valiosa no desenvolvimento de novos sistemas catalíticos. No geral, 2-Diciclohexilfosfino-2',6'-dimetoxibifenil é reconhecido por sua eficácia em promover várias transformações químicas na química orgânica sintética.

Fórmula: C₂₆H₃₅O₂P

InChI: InChI=1S/C26H35O2P/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21/h9-11,16-21H,3-8,12-15H2,1-2H3

Chave InChI: InChIKey=VNFWTIYUKDMAOP-UHFFFAOYSA-N

SMILES: P(C1=C(C=CC=C1)C2=C(OC)C=CC=C2OC)(C3CCCCC3)C4CCCCC4

Sinónimos:

• (2,6-Dimethoxy-1,1′-biphenyl-2-yl)dicyclohexylphosphine
• 2-(Dicyclohexylphosphino)-2′,6′-dimethoxy-1,1′-biphenyl
• 2-Dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl
• 2-Dicyclohexylphosphino-2',6'-dimethoxybipheny
• 2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl
• Dicyclohexyl(2',6'-Dimethoxybiphenyl-2-Yl)Phosphane
• Dicyclohexyl(2′,6′-dimethoxy[1,1′-biphenyl]-2-yl)phosphine
• Dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine
• Dicyclohexyl({2-[(2,6-Dimethoxyphenyl)Methyl]Phenyl}Methyl)Phosphane
• Phosphine, dicyclohexyl(2′,6′-dimethoxy[1,1′-biphenyl]-2-yl)-
• S-Phos
• SPhos 97%
• 2-Dicyclohexylphosphino-2',6'-diMethoxy-1,1'-biphenyl,98% Sphos
• 2-DicyclohexylphosphiNA-2',6'-diMethoxybiphenyl
• Dicyclohexyl(2',6'-dimethoxybiphenyl-2-yl)phosphine
• 2-Dicyclohexylphosphino-2&acute
• REF DUPL: S-PHOS
• 2 - dicyclohexyl phosphine - 2 ', 6 '- diMethoxy - 1, 1' - two PCB
• S-Phos, ChemDose(R) tablets
• S-Phos impregnated tablets, ChemDose(R), S-Phos tablets, 2-Dicyclohexylphosphino-2μ,6μ-dimethoxybiphenyl impregnated tablets
• 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl
• 6&acute
• 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl, min. 98%
• 98% SPhos
• 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 98+%
• 2-Dicyclohexylphosphino-2’,6’-dimethoxy-1,1’-biphenyl (S-Phos)
• S-PHOS, 2-Dicyclohexylphosphino-2,6-di-Methyloxy-1,1-biphenyl
• Phosphine,dicyclohexyl(2',6'-dimethoxy[1,1'-biphenyl]-2-yl)-
• 2-Dicyclohexylphosphino-2', 6-diMethoxybihenyl
• 2-DICYCLOHEXYLPHOSPHINO-2',6'-DIMETHOXY-1,1'-BIPHENYL, MIN. 98% S-PHOS
• 2-Dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl, min. 98%
• 2-(Dicyclohexylphosphanyl)-2',6'-dimethoxybiphenyl
• 2-Dicyclohexylphosphino-2',6'-diMethoxybiphenyl, 6'-diMethoxybiphenyl
• SPhos, >=98%
• 2-Dicyclohexylphosphino-2',6'-
• S-Phos, ChemDose? tablets
• -diMethoxybiphenyl
• Dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane
• Dicyclohexyl(2',6'-diMethoxy-[1,1'-biphenyl]-2-yl)phosphine

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

CAS: 657408-07-6

Fórmula: C₂₆H₃₅O₂P

Pureza: >98.0%(HPLC)

Cor e Forma: White to Almost white powder to crystal

Peso molecular: 410.54

Ref: 3B-D5036

2-Dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl, min. 98% SPhos

CAS: 657408-07-6

2-Dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl, min. 98% SPhos

Fórmula: C₂₆H₃₅O₂P

Pureza: min. 98%

Cor e Forma: white xtl.

Peso molecular: 410.53

Ref: 08-15-1143

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

CAS: 657408-07-6

Fórmula: C₂₆H₃₅O₂P

Pureza: 98%

Cor e Forma: Solid

Peso molecular: 410.5287

Ref: IN-DA0033A9

2-(Dicyclohexylphosphanyl)-2',6'-dimethoxybiphenyl

CAS: 657408-07-6

2-(Dicyclohexylphosphanyl)-2',6'-dimethoxybiphenyl

Fórmula: C₂₆H₃₅O₂P

Pureza: 98%

Cor e Forma: white crystalline powder

Peso molecular: 410.53g/mol

Ref: 54-OR40584

2-Dicyclohexylphosphino-2'',6''-dimethoxybiphenyl

CAS: 657408-07-6

Fórmula: C₂₆H₃₅O₂P

Pureza: ≥ 98.0%

Cor e Forma: White to off-white powder

Peso molecular: 410.54

Ref: 7W-GK5403

Dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine

CAS: 657408-07-6

Fórmula: C₂₆H₃₅O₂P

Pureza: 98.0%

Cor e Forma: Solid, Powder or Crysalline Powder or Solid or Chunks

Peso molecular: 410.538

Ref: 10-F078390

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

CAS: 657408-07-6

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl is a fluorescent chemical that has been used to study interactions of fatty acids and halides. It is also used in the synthesis of palladium complexes, which have been shown to be effective for hydrogenation reactions. 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl can be synthesized from 2,6-dichlorobenzaldehyde and dicyclohexylphosphine by the addition of trifluoroacetic acid. The synthesis proceeds via a substitution reaction with methoxy groups on the aromatic ring. This product fluoresces under ultraviolet light at 351 nm.

Fórmula: C₂₆H₃₅O₂P

Pureza: Min. 95%

Cor e Forma: Powder

Peso molecular: 410.53 g/mol

Ref: 3D-FD31495

S-Phos

Produto Controlado

CAS: 657408-07-6

Applications S-Phos is a catalyst that is used in the preparation of thiadiazoles as DGAT1 inhibitors with potential in metabolic diseases treatment.
References Mougenot, P., et la.: Bioorg. Med. Chem. Lett., 22, 2497 (2012);

Fórmula: C₂₆H₃₅O₂P

Cor e Forma: Neat

Peso molecular: 410.53

Ref: TR-S681720

S-Phos (2-Dicyclohexylphosphino-2,6-Dimethoxybiphenyl) extrapure, 98%

CAS: 657408-07-6

Fórmula: C₂₆H₃₅O₂P

Pureza: min.98%

Cor e Forma: White, Crystalline powder

Peso molecular: 410.53

Ref: SR-77061