CAS 884879-24-7

estereoisómero de [1,3-Bis[2,6-bis(1-metiletil)fenil]-2-imidazolidinilideno]cloro[(1,2,3-η)-1-fenil-2-propen-1-il]paládio

Descrição:

A substância química conhecida como "estereoisómero de [1,3-Bis[2,6-bis(1-metiletil)fenil]-2-imidazolidinilideno]cloro[(1,2,3-η)-1-fenil-2-propen-1-il]paládio" com número CAS 884879-24-7 é um complexo de paládio que apresenta um ligante imidazolidinilideno quiral. Este composto é caracterizado pela sua coordenação de paládio a um ligante cloro e a um grupo vinilo, que faz parte de uma estrutura mais complexa envolvendo substituintes arila volumosos. A presença de estereoisomerismo indica que o composto pode existir em múltiplos arranjos espaciais, o que pode influenciar significativamente sua reatividade e interação com outras moléculas. Esses complexos de paládio são frequentemente utilizados em catálise, particularmente em reações de acoplamento cruzado e outras transformações orgânicas, devido à sua capacidade de facilitar a formação de ligações carbono-carbono. A hindrance estérica proporcionada pelos substituintes volumosos melhora a seletividade e pode afetar a eficiência geral dos processos catalíticos. Compreender a estereoquímica deste composto é crucial para otimizar sua aplicação em química sintética.

Fórmula: NeolystCX₃₂

InChI: InChI=1S/C27H38N2.C9H9.ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-2-6-9-7-4-3-5-8-9;;/h9-14,18-21H,15-16H2,1-8H3;2-8H,1H2;1H;/q-2;-1;;+4/p-1

Chave InChI: InChIKey=SWCINQFDTMPPRM-UHFFFAOYSA-M

SMILES: [Cl-][Pd+4]12([CH-]([CH]1=[CH2]2)C3=CC=CC=C3)=[C-2]4N(CCN4C5=C(C(C)C)C=CC=C5C(C)C)C6=C(C(C)C)C=CC=C6C(C)C

Sinónimos:

• Chloro[(1,2,3-N)-3-Phenyl-2-Propenyl][1,3-Bis(2,6-Di-I-Propylphenyl)-4,5-Dihydroimidazol-2-Ylidene]Palladium(Ii)
• Chloro[(1,2,3-Η)-3-Phenyl-2-Propenyl][1,3-Bis(2,6-Di-I-Propylphenyl)-4,5-Dihydroimidazol-2-Ylidene]Palladium(II)
• Palladium, [1,3-bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]chloro[(1,2,3-η)-1-phenyl-2-propen-1-yl]-, stereoisomer
• Palladium, [1,3-bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]chloro[(1,2,3-η)-3-phenyl-2-propenyl]-, stereoisomer
• Phenylallylchloro-[1,3-Bis(Diisopropylphenyl)-2-Imidazolidinylidene]Palladium(Ii)
• Umicore CX32
• stereoisomer of [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]chloro[(1,2,3-η)-1-phenyl-2-propen-1-yl]palladium
• [1,3-Bis(2,6-di-isopropylphenyl)-4,5-dihydroimidazol-2-ylidene]chloro][3-phenylallyl]palladium(II) 95%
• Chloro[(1,2,3-n)-3-phenyl-2-propenyl][1,3-bis(2,6-di-i-propylphenyl)-4,
• Chloro[(1,2,3-n)-3-phenyl-2-propenyl][1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II), min. 97%
• Chloro[(1,2,3-η)-3-phenyl-2-propenyl][1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium (II), min. 97%
• Chloro[(1,2,3-n)-3-phenyl-2-propenyl][1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II),min.97%
• 5-dihydroimidazol-2-ylidene]palladium(II), min. 97%
• [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]chloro[(1,2,3-η)-3-phenyl-2-propenyl]palladium
• Chloro[(1,2,3-η)-3-phenyl-2-propenyl][1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroiMidazol-2-ylidene]palladiuM(II),97%
• UMicore CX32, 16% Pd, Product of UMicore

Chloro[(1,2,3-≈)-3-phenyl-2-propenyl][1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II), min. 97%

CAS: 884879-24-7

Chloro[(1,2,3-η)-3-phenyl-2-propenyl][1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II), min. 97%

Fórmula: C₃₆H₄₇ClN₂Pd

Pureza: min. 97%

Cor e Forma: yellow microxtls.

Peso molecular: 648.24626

Ref: 08-46-0274

[1,3-Bis(2,6-di-isopropylphenyl)-4,5-dihydroimidazol-2-ylidene]chloro][3-phenylallyl]palladium(II)

CAS: 884879-24-7

Fórmula: C₃₆H₄₄ClN₂Pd

Pureza: 98%

Cor e Forma: Solid

Peso molecular: 646.6210

Ref: IN-DA003CQN

Chloro[(1,2,3-eta)-3-Phenyl-2-Propenyl][1,3-Bis(2,6-di-i-propylPhenyl)-4,5-Dihydroimidazol-2-Ylidene]Palladium(II)

CAS: 884879-24-7

Chloro[(1,2,3-eta)-3-Phenyl-2-Propenyl][1,3-Bis(2,6-di-i-propylPhenyl)-4,5-Dihydroimidazol-2-Ylidene]Palladium(II)

Pureza: 98%

Peso molecular: 649.60g/mol

Ref: 54-IN10391