CAS 887919-35-9

Diclorobis[di-terc-butil(4-dimetilaminofenil)fosfino]paládio(II)

Descrição:

Diclorobis[di-terc-butil(4-dimetilaminofenil)fosfino]paládio(II) é um complexo de paládio caracterizado pela sua coordenação de paládio com dois ligandos de fosfina bidentados. A estrutura apresenta um centro de paládio coordenado a dois íons de cloreto e dois ligandos de fosfina volumosos, que são derivados da di-terc-butilo(4-dimetilaminofenil)fosfina. Este complexo é notável por suas potenciais aplicações em catálise, particularmente em reações de acoplamento cruzado, devido às favoráveis propriedades eletrônicas e estéricas conferidas pelos ligandos de fosfina. A presença do grupo dimetilamino aumenta a capacidade de doação de elétrons dos ligandos, o que pode influenciar a reatividade do centro de paládio. Além disso, os volumosos grupos terc-butil proporcionam impedimento estérico, o que pode ajudar a estabilizar o complexo e prevenir reações secundárias indesejadas. No geral, este composto exemplifica a versatilidade dos complexos de paládio na síntese orgânica e na ciência dos materiais, mostrando a interação entre o design de ligandos e a atividade catalítica.

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

InChI: InChI=1/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H;/q;;;;+2/p-2

SMILES: CC(C)(C)P(c1ccc(cc1)N(C)C)C(C)(C)C.CC(C)(C)P(c1ccc(cc1)N(C)C)C(C)(C)C.Cl.Cl.[Pd]

Sinónimos:

• 4-(Di-tert-butylphosphino)-N,N-dimethylaniline-dichloropalladium (2:1)
• 4-(di-tert-butylphosphanyl)-N,N-dimethylaniline-dichloropalladium (2:1)
• Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
• Dichlorobis(di-tert-butyl-4-dimethylaminophenylphosphine) palladium(II)
• (A-taPhos)2PdCl2
• (AmPhos)2PdCl2

Bis[di-tert-butyl(4-dimethylaminophenyl)phosphine]dichloropalladium(II)

CAS: 887919-35-9

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

Pureza: >98.0%(T)

Cor e Forma: Light yellow to Yellow to Orange powder to crystal

Peso molecular: 708.08

Ref: 3B-B6255

Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II), Pd 15%

CAS: 887919-35-9

Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II) is a highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling with aryl halides including 5- and 6-membered heteroaryl chlorides. This Thermo Scientific brand product was originally part of the Alfa Aesar product por

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

Peso molecular: 708.08

Ref: 02-045511

Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos

CAS: 887919-35-9

Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos

Fórmula: (C₁₆H₂₈NP)₂PdCl₂

Pureza: min. 98%

Cor e Forma: yellow pwdr.

Peso molecular: 708.07

Ref: 08-46-0825

Bis(4-(di-tert-Butylphosphanyl)-N,N-dimethylaniline); palladium chloride

CAS: 887919-35-9

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

Pureza: 98%

Cor e Forma: Solid

Peso molecular: 708.0740

Ref: IN-DA0035ZO

Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride

CAS: 887919-35-9

Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride

Fórmula: ·2C₁₆H₂₈NP·Cl₂Pd

Pureza: 97%

Cor e Forma: yellow solid

Peso molecular: 708.07396g/mol

Ref: 54-OR17048

PdCl2(amphos)2 (HPMC encapsulated)

CAS: 887919-35-9

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

Cor e Forma: White to Light yellow capsule

Peso molecular: 708.08

Ref: 3B-R0306

Bis(4-(di-tert-Butylphosphanyl)-N,N-dimethylaniline)-palladium chloride

CAS: 887919-35-9

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

Pureza: 98%

Cor e Forma: Solid

Peso molecular: 708.08

Ref: 10-F051339

Bis(4-(di-tert-butylphosphino)-N,N-dimethylbenzenamine) palladium dichloride

Produto Controlado

CAS: 887919-35-9

Bis(4-(di-tert-butylphosphanyl)-N,N-dimethylaniline) is a boronic acid that has been used as a surfactant in organic chemistry. It is hydrophobic and has hydrogen bonding interactions with other molecules. Bis(4-(di-tert-butylphosphanyl)-N,N-dimethylaniline) is also a proton acceptor and can form stable complexes with metal ions such as palladium chloride. This compound is kinase selective and can be used to inhibit tyrosine kinases by binding to the ATP binding site of the enzyme's kinase domain. The functional groups of this compound are able to undergo cross-coupling reactions with other functional groups that have been activated by a reagent such as palladium chloride. Bis(4-(di-tert-butylphosphanyl)-N,N-dimethylaniline) has been used in high

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

Pureza: Min. 95%

Cor e Forma: Powder

Peso molecular: 708.07 g/mol

Ref: 3D-FB72418