Di-tert-butyl azodicarboxylate, 98%

CAS: 870-50-8

Ref. 02-L00294

Informação sobre produto

• Nome: Di-tert-butyl azodicarboxylate, 98%
• Sinónimos: N-[(tert-butoxycarbonyl)imino](tert-butoxy)formamide, 1,2-Diazenedicarboxylic acid, 1,2-bis(1,1-dimethylethyl) ester, Azodicarboxylic acid di-tert-butyl ester, Bis(1,1-dimethylethyl)azodicarboxylate, Dbad, Di-Tert-Butyl Diazene-1,2-Dicarboxylate, Di-tert-butyl azodiformate, Di-tert-butyl diazodicarboxylate, Diazenedicarboxylic acid, bis(1,1-dimethylethyl) ester, Formic acid, azodi-, di-tert-butyl ester, NSC 109889, di-tert-butyl (E)-diazene-1,2-dicarboxylate, Di-tert-butyl azodicarboxylate

Descrição

Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates. It is also used in the electrophilic amination of beta-keto esters catalyzed by an axially chiral guanidine. It serves as a precursor in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such as L-proline or (S)-2-pyrrolidinyl tetrazole. It is also utilized in the asymmetric Friedel-Crafts amination through a chiral organocatalyst. Further, it acts as a reactant for preparation of hexapeptide key fragments through stereo selective selenocyclization/oxidative deselenylation reactions. In addition to this, it is employed as a starting material in the synthesis of pyrroloisoquinoline template through stereoselective N-acyliminium-mediated cyclization and enolate amination for preparation of peptidomimetic compounds and Barbier-type propargylation reactions. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Marca: Alfa Aesar By Thermo Fisher Scientific

Propriedades químicas

• Peso molecular: 230.26
• Fórmula: C₁₀H₁₈N₂O₄
• Pureza: 98%
• Cor/forma: Yellow, Crystals or powder or crystalline powder or fused solid or flakes
• Chave InChI: QKSQWQOAUQFORH-UHFFFAOYSA-N