(R)-(“)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane
CAS: 325168-89-6
Ref. 3D-ANA16889
1g | A consultar |
Informação sobre produto
- (R)-XylPhanePHOS
- Phosphine, 1,1′-tricyclo[8.2.2.2<sup>4,7</sup>]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-bis(3,5-dimethylphenyl)-, stereoisomer
- Phosphine, tricyclo[8.2.2.2<sup>4,7</sup>]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[bis(3,5-dimethylphenyl)-, stereoisomer
- R-Xylyl-Phanephos
- Tricyclo[8.2.2.24,7]Hexadeca-1(12),4,6,10,13,15-Hexaene-5,11-Diylbis[Bis(3,5-Dimethylphenyl)Phosphane]
- stereoisomer of 1,1′-Tricyclo[8.2.2.2<sup>4,7</sup>]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine
- Phosphine, 1,1′-tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-bis(3,5-dimethylphenyl)-, stereoisomer
- stereoisomer of 1,1′-Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine
- Phosphine, tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[bis(3,5-dimethylphenyl)-, stereoisomer
(R)-(“)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane is an enantioselective catalyst for the asymmetric synthesis of amines with high yields and enantioselectivities. It has been shown to be effective in the synthesis of a variety of amines, including those containing electron-donating substituents such as nitro or cyano groups. The catalytic activity of (R)-(“)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane is dependent on the presence of Lewis acids such as AlCl3 or FeCl3 and on its steric bulk.
Propriedades químicas
Consulta técnica sobre: 3D-ANA16889 (R)-(“)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane
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