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Phenyl groups are often found in molecules that have optimal conformational geometry, with the phenyl ring occupying a central position and the substituents on either side. This molecule is one such example. The conformational interconversion of this molecule was studied by x-ray diffraction analysis, which revealed that it has two possible conformations. One conformation has the phenyl group in an axial orientation, while the other conformation has the phenyl group in a pseudoaxial orientation. The X-ray analysis showed that both conformations are present in solution, but only one is observed in crystalline form. A molecular modeling study showed that the pseudoaxial conformation is more stable than the axial conformation because of steric interactions between substituents on adjacent carbons.
Propriedades químicas
Consulta técnica sobre: 3D-DAA73329 5,5-Bis(bromomethyl)-2-phenyl-1,3-dioxane
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