tert-Butyl(triphenylphosphoranylidene)acetate

CAS: 35000-38-5

Ref. 3D-FB106311

Informação sobre produto

• Nome: tert-Butyl(triphenylphosphoranylidene)acetate
• Sinónimos: (Triphenyl-λ⁵-phosphanylidene)acetic acid tert-butyl ester, (Triphenylphosphoranylidene)acetic acid tert-butyl ester, (tert-Butoxycarbonylmethylene)triphenylphosphoran, (tert-Butoxycarbonylmethylene)triphenylphosphorane, 1,1-Dimethylethyl (triphenylphosphoranylidene)acetate, 1,1-Dimethylethyl 2-(triphenyl-λ5-phosphanylidene)acetate, Acetic acid, (triphenylphosphoranylidene)-, 1,1-dimethylethyl ester, Acetic acid, 2-(triphenylphosphoranylidene)-, 1,1-dimethylethyl ester, NSC 82469, Tert-Butyl (Triphenyl-Lambda~5~-Phosphanylidene)Acetate, Triphenyl(tert-butoxycarbonylmethylene)phosphorane, tert-Butyl (triphenylphosphoranylidene)acetate, tert-Butyl (triphenylphosphoranylidene)acetate~(Carbo-tert-butoxymethylene)triphenylphosphorane, tert-Butyl 2-(triphenylphosphaneylidene)acetate, tert-Butyl 2-(triphenylphosphoranylidene)acetate, tert-Butyl triphenylphosphoranylidenacetate

Descrição

Tert-Butyl (triphenylphosphoranylidene)acetate is a tert-butyl substituted tricyclic compound, with a tetraponerine skeleton. It is synthesized from the reaction of acetyl chloride and triphenylphosphoranylidene dichloride in the presence of an amine such as piperidine or 1,4-diazabicyclo[2.2.2]octane (DABCO). The tert-butyl group acts as an electron donor and helps to stabilize the carbocation intermediate. Tert-Butyl (triphenylphosphoranylidene)acetate can be used as a reagent in the synthesis of various secondary amides and tertiary amines, as well as olefination reactions. This compound has been shown to undergo β-unsaturated esterification reactions with α,β-unsaturated carboxylic acids in the presence of aluminum

• Marca: Biosynth

Propriedades químicas

• Peso molecular: 376.43 g/mol
• Fórmula: C₂₄H₂₅O₂P
• Pureza: Min. 95%
• Cor/forma: Powder
• InChI: InChI=1S/C24H25O2P/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22/h4-19H,1-3H3
• Chave InChI: InChIKey=ZWZUFQPXYVYAFO-UHFFFAOYSA-N
• SMILES: CC(C)(C)OC(=O)C=P(c1ccccc1)(c1ccccc1)c1ccccc1