(2-Bromophenyl)diphenylphosphine

CAS: 62336-24-7

Ref. 3D-FB60780

Informação sobre produto

• Nome: (2-Bromophenyl)diphenylphosphine
• Sinónimos: (2-Bromophenyl)(Diphenyl)Phosphane, (2-Bromophenyl)-diphenylphosphane, (o-Bromophenyl)diphenylphosphine, 1-Bromo-2-(diphenylphosphino)benzene, 2-(Diphenylphosphino)-1-bromobenzene, 2-(Diphenylphosphino)bromobenzene, 2-(Diphenylphosphino)phenyl bromide, Phosphine, (2-bromophenyl)diphenyl-, Phosphine, (o-bromophenyl)diphenyl-

Descrição

(2-Bromophenyl)diphenylphosphine is a ligand that can be used in the activation of alkyl halides. It has been shown to promote the bond cleavage of primary alcohols and hydroxyl groups. (2-Bromophenyl)diphenylphosphine is also an ancillary ligand in molecular orbitals, which aids in stabilizing the molecular orbital. The nature of this ligand has been studied using x-ray diffraction methods. It has been found that the bond lengths and angles are dependent on the substituents on its phenyl rings, with shorter bonds and larger angles for more substituted derivatives. This ligand can also participate in nucleophilic attack reactions with halides to form a phosphonium ion intermediate.

• Marca: Biosynth

Propriedades químicas

• Peso molecular: 341.18 g/mol
• Fórmula: C₁₈H₁₄BrP
• Pureza: Min. 95%
• InChI: InChI=1S/C18H14BrP/c19-17-13-7-8-14-18(17)20(15-9-3-1-4-10-15)16-11-5-2-6-12-16/h1-14H
• Chave InChI: InChIKey=XIONUQPOXCUMMB-UHFFFAOYSA-N
• SMILES: Brc1ccccc1P(c1ccccc1)c1ccccc1