(S)-Ru(OAc)2(BINAP)
CAS: 261948-85-0
Ref. 3D-FR164040
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Informação sobre produto
- Ruthenium, bis(acetato-κO,κO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]-, (OC-6-22)-
The mechanism of the Ru-catalyzed hydrogenation of 2-butynoic acid to butyric acid is a three-step process. The first step involves the addition of a proton and an electron from H2O to the substrate, forming a carbonyl compound. The second step involves the transfer of a hydride ion from Ru to the carbonyl compound, forming an alcohol. The third step involves the elimination of H2O with simultaneous formation of a double bond and release of CO2. This reaction has been shown to be catalytic in acidic conditions, recycling Ru and producing no emissions. The active catalyst is (S)-Ru(OAc)2(BINAP). The major functionalities are mesoporous silica and tiglic acid, which enhance reactivity by providing pairwise interactions between substrates and catalyst.
Propriedades químicas
Consulta técnica sobre: 3D-FR164040 (S)-Ru(OAc)2(BINAP)
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