2-BROMOVINYLTRIMETHYLSILANE

CAS: 41309-43-7

Ref. 3H-SIB1910.1

Informação sobre produto

• Nome: 2-BROMOVINYLTRIMETHYLSILANE
• Sinónimos: 2-(TRIMETHYLSILYL)VINYLBROMIDE, [(E)-2-Bromovinyl](trimethyl)silane, Silane, [(E)-2-bromoethenyl]trimethyl-, Silane, (2-bromoethenyl)trimethyl-, (2-Bromovinyl)trimethylsilane

Descrição

Alkenylsilane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
2-Bromovinyltrimethylsilane; 2-(Trimethylsilyl)vinylbromide
Contains 10-15% cis-isomerSlowly decomposes above 60 °C yielding ethyleneUseful for cross-coupling to 2-substituted vinylsilanesPotential for cross-coupling protocols to yield β-substituted vinylsilanesExtensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

• Marca: Gelest

Propriedades químicas

• Peso molecular: 179.13
• Fórmula: C₅H₁₁BrSi
• Pureza: 97%
• Cor/forma: Straw Liquid