(4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol

CAS: 137365-09-4

Ref. TR-D479455

Informação sobre produto

• Nome: (4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol
• Sinónimos: (4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol, (4R,5R)-2,2-Dimethyl-α4,α4,α5,α5-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol, (4R-trans)-2,2-Dimethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol
• Marca: TRC
• Descrição: Applications (4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol, is a privileged ligand analogue of TADDOLs. It can be broadly used in asymmetric synthesis. It is also shown that the titanium TADDOLate catalysts have broad application towards carbonyl addition and cycloaddition.References Seebach, D., et al.: Ange. Chem. Inter. Ed., 40, 92, (20010

Propriedades químicas

• Peso molecular: 666.802
• Fórmula: C₄₇H₃₈O₄
• Cor/forma: Neat
• InChI: InChI=1S/C47H38O4/c1-45(2)50-43(46(48,39-23-19-31-11-3-7-15-35(31)27-39)40-24-20-32-12-4-8-16-36(32)28-40)44(51-45)47(49,41-25-21-33-13-5-9-17-37(33)29-41)42-26-22-34-14-6-10-18-38(34)30-42/h3-30,43-44,48-49H,1-2H3/t43-,44-/m1/s1
• Chave InChI: InChIKey=QWADMRIAKWGVBF-NDOUMJCMSA-N
• SMILES: CC1(C)O[C@@H](C(O)(c2ccc3ccccc3c2)c2ccc3ccccc3c2)[C@H](C(O)(c2ccc3ccccc3c2)c2ccc3ccccc3c2)O1