2,​3,​4-​Triacetate 1-​(2,​2,​2-​Trichloroethanimidat​e) 6-​O-​(2,​3,​4,​6-​Tetra-​O-​acetyl-​b-​D-​glucopyranosyl)​-b-​D-​glucopyranose

CAS: 888945-73-1

Ref. TR-T542695

Informação sobre produto

• Nome: 2,​3,​4-​Triacetate 1-​(2,​2,​2-​Trichloroethanimidat​e) 6-​O-​(2,​3,​4,​6-​Tetra-​O-​acetyl-​b-​D-​glucopyranosyl)​-b-​D-​glucopyranose
• Sinónimos: [(2R,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-[[(2R,3R,4S,5R,6S)-3,4,5-triacetyloxy-6-(2,2,2-trichloroethanimidoyl)oxyoxan-2-yl]methoxy]oxan-2-yl]methyl acetate
• Marca: TRC
• Descrição: Applications 2,​3,​4-​Triacetate 1-​(2,​2,​2-​Trichloroethanimidat​e) 6-​O-​(2,​3,​4,​6-​Tetra-​O-​acetyl-​β-​D-​glucopyranosyl)​-β-​D-​glucopyranose is an intermediate in the synthesis of Guaiacol-beta-D-gentiobioside (G245570), which is a Guaiacol Conjugate, that has shown to present in fermentation of grapes that had been exposed to bushfire smoke and can potentially yield unpalatable, smoke-affected wine.References Hayasaka, Y.m et al.: J. Arg. Food Chem., Vol. 58, Issue 4, P: 2076; 2081 (2010)

Propriedades químicas

• Peso molecular: 780.94
• Fórmula: C₂₈H₃₆Cl₃NO₁₈
• Cor/forma: Neat
• InChI: InChI=1S/C28H36Cl3NO18/c1-10(33)40-8-17-19(42-11(2)34)21(44-13(4)36)23(46-15(6)38)25(48-17)41-9-18-20(43-12(3)35)22(45-14(5)37)24(47-16(7)39)26(49-18)50-27(32)28(29,30)31/h17-26,32H,8-9H2,1-7H3/t17-,18-,19-,20-,21+,22+,23-,24-,25-,26+/m1/s1
• Chave InChI: InChIKey=BQWSDTBLBHIXEF-SVRUBWSYSA-N
• SMILES: CC(=O)OC[C@H]1O[C@@H](OC[C@H]2O[C@@H](OC(=N)C(Cl)(Cl)Cl)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H]2OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H]1OC(C)=O