CAS 116128-29-1: Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)

Description: Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) is a coordination complex featuring a ruthenium center coordinated to a bidentate ligand derived from binaphthyl and phosphine groups. This compound is characterized by its chiral nature, attributed to the (R)-enantiomer of the binaphthyl ligand, which imparts specific stereochemical properties. The presence of diacetato ligands indicates that it has two acetate groups, which can influence its solubility and reactivity. The bulky di-p-tolylphosphino groups enhance the steric and electronic properties of the complex, making it suitable for various catalytic applications, particularly in asymmetric synthesis. The ruthenium center typically exhibits a +2 oxidation state, contributing to its stability and reactivity in catalytic cycles. This compound is of interest in organometallic chemistry and catalysis, especially in processes such as hydrogenation and cross-coupling reactions, where its chiral environment can facilitate the formation of enantiomerically enriched products. Overall, its unique structural features make it a valuable compound in synthetic organic chemistry.

Formula: C₅₂H₄₆O₄P₂Ru

Synonyms:

• (R)-Ru(OAc)2(T-BINAP)

Ru(OAc)2[(R)-tolbinap]

CAS: 116128-29-1

• Formula: C₅₂H₄₆O₄P₂Ru
• Color and Shape: Dark green to Dark red to Black powder to crystal
• Molecular weight: 897.95

Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)₂[(R)-tolbinap]

CAS: 116128-29-1

Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-tolbinap]

• Formula: C₅₂H₄₆O₄P₂Ru
• Color and Shape: brown pwdr.
• Molecular weight: 897.94

Ruthenium, bis(acetato-κO,κO')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)phosphine-κP]]-, (OC-6-22)-

CAS: 116128-29-1

• Formula: C₅₂H₄₆O₄P₂Ru
• Purity: 97%
• Molecular weight: 897.9368

Ru(OAc)2[(R)-tolbinap]

CAS: 116128-29-1

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• Formula: C₅₂H₄₆O₄P₂Ru
• Purity: Min. 95%
• Molecular weight: 897.95 g/mol