CAS 14319-13-2: (OC-6-11)-Tris(2,2,6,6-tetramethyl-3,5-heptanedionato-κO3,κO5)lanthanum
Description:(OC-6-11)-Tris(2,2,6,6-tetramethyl-3,5-heptanedionato-κO3,κO5)lanthanum, commonly referred to as La(TMHD)3, is a coordination compound of lanthanum. This substance features a lanthanum ion coordinated with three bidentate ligands derived from 2,2,6,6-tetramethyl-3,5-heptanedione, which is known for its chelating ability. The compound typically exhibits a high degree of thermal stability and solubility in organic solvents, making it useful in various applications, including as a precursor in the synthesis of lanthanum oxide and other lanthanide materials. Its structure is characterized by a central lanthanum ion surrounded by three chelating ligands, which stabilize the metal center and influence its reactivity. The presence of bulky alkyl groups in the ligands contributes to the steric hindrance, affecting the compound's interaction with other molecules. Overall, La(TMHD)3 is significant in materials science and catalysis, particularly in the development of advanced materials and nanostructures.
Formula:C33H57LaO6
InChI:InChI=1S/3C11H19O2.La/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7H,1-6H3;/q3*-1;+3
InChI key:InChIKey=BVHALGVWBCQFGY-UHFFFAOYSA-N
SMILES:O1=C([CH-]C(=O[La+3]123(O=C([CH-]C(=O2)C(C)(C)C)C(C)(C)C)O=C([CH-]C(=O3)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C
- Synonyms:
- (OC-6-11)-Tris(2,2,6,6-tetramethyl-3,5-heptanedionato-κO<sup>3</sup>,κO<sup>5</sup>)lanthanum
- 2,2,6,6-Tetramethylheptane-3,5-Dione-Lanthanum (3:1)
- 3,5-Dihydroxy-2,2,6,6-Tetramethylheptane-3,4,5-Triyl-Lanthanum (3:1)
- 3,5-Heptanedione, 2,2,6,6-tetramethyl-, lanthanum complex
- Lanthanum tris(2,2,6,6-tetramethylheptane-3,5-dionate)
- Lanthanum tris(dipivaloylmethanate)
- Lanthanum, tris(2,2,6,6-tetramethyl-3,5-heptanedionato)-
- Lanthanum, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O')-, (OC-6-11)-
- Lanthanum, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-κO<sup>3</sup>,κO<sup>5</sup>)-, (OC-6-11)-
- Lanthanum, tris(dipivaloylmethanato)-
- See more synonyms
- NSC 174900
- Pb(Tmhd)2
- Resolve-Al(Tm) La
- Resolve-al la
- Tris(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Lanthanum
- Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lanthanum (III)
- Tris(dipivaloylmethanato)lanthanum
- Tris(tetramethylheptanedionato)lanthanum
- Lanthanum, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-κO3,κO5)-, (OC-6-11)-
- (OC-6-11)-Tris(2,2,6,6-tetramethyl-3,5-heptanedionato-κO3,κO5)lanthanum