CAS 14647-23-5: (Bis(diphenylphosphino)ethane)dichloronickel

Description:(Bis(diphenylphosphino)ethane)dichloronickel, commonly referred to as NiCl2(dppeth), is a coordination compound featuring nickel in a +2 oxidation state coordinated to two diphenylphosphinoethane ligands and two chloride ions. This compound typically exhibits a square planar geometry due to the d8 electron configuration of nickel, which is characteristic of many nickel(II) complexes. The diphenylphosphinoethane ligands contribute to the overall stability and solubility of the complex in organic solvents. NiCl2(dppeth) is often utilized in catalysis, particularly in cross-coupling reactions and other organic transformations, due to its ability to facilitate the transfer of electrons and promote bond formation. The presence of phosphorus donor atoms enhances the reactivity of the nickel center, making it an important compound in organometallic chemistry. Additionally, the compound may exhibit interesting thermal and photochemical properties, which can be relevant in various applications, including materials science and catalysis.

Formula:C₂₆H₂₄Cl₂NiP₂

InChI:InChI=1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

InChI key:InChIKey=XXECWTBMGGXMKP-UHFFFAOYSA-L

SMILES:[Cl-][Ni+2]1([Cl-])[P](C=2C=CC=CC2)(C=3C=CC=CC3)CC[P]1(C=4C=CC=CC4)C=5C=CC=CC5

Synonyms:
(Bis(diphenylphosphino)ethane)dichloronickel
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
1,2-Bis(diphenylphosphino)ethanedichloronickel
1,2-Bis(diphenylphosphino)ethanenickel dichloride
1,2-Ethylenebis(diphenylphosphine)nickel dichloride
DPPE.NiCl2
Dichloro-1,2-bis(diphenylphosphino)ethanenickel(II)
Dichloro[1,2-bis(diphenylphosphino)ethane]nickel
Dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II)
Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P′]nickel
See more synonyms
Dichloro[1,2-ethanediylbis[diphenylphosphine]]nickel
Dichloro[ethylenebis[diphenylphosphine]]nickel
Dichlorobis[(diphenylphosphino)ethane]nickel(II)
Nickel 1,2-Bis(diphenylphosphino)ethane dichloride
Nickel, dichloro[1,2-ethanediylbis[diphenylphosphine-κP]]-, (SP-4-2)-
Nickel, dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P′]-, (SP-4-2)-
Nickel, dichloro[ethylenebis[diphenylphosphine]]-
Nickel, dichloro[ethylenebis[diphenylphosphine]]-, cis-
Phosphine, 1,2-ethanediylbis[diphenyl-, nickel complex
[1,2-Bis(Diphenylphosphino)Ethane]Dichloronickel(Ii)
[1,2-Bis(diphenylphosphino)ethane]dichloronickel
cis-(1,2-Bis(diphenylphosphino)ethane)dichloronickel

Found 8 products.

Product data	Purity	Price range	Estimated delivery
Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98% REF: 02-013932CAS: 14647-23-5	98%	48.00 €	Fri 21 Mar 25
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride, 99% REF: 08-28-0030CAS: 14647-23-5	99%	56.00 €~427.00 €	Mon 24 Mar 25
1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride REF: IN-DA0032KCCAS: 14647-23-5	98%	22.00 €~184.00 €	Thu 27 Mar 25
1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride REF: 54-IN10319CAS: 14647-23-5	98%+	75.00 €~269.00 €	Fri 28 Mar 25
[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride REF: 3B-B2225CAS: 14647-23-5	>96.0%(T)	28.00 €~221.00 €	Tue 01 Apr 25
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride REF: 10-F077791CAS: 14647-23-5	96.0%	To inquire	Tue 08 Apr 25
[Bis(diphenylphosphino)ethane]dichloronickel REF: TR-B430455CAS: 14647-23-5	- - -	91.00 €~111.00 €	Tue 08 Apr 25
[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride REF: 3D-FB60935CAS: 14647-23-5	Min. 95%	To inquire	Thu 08 May 25

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98%

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Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98%

CAS:14647-23-5

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis …

Formula:

C₂₆H₂₄Cl₂NiP₂

Purity:

98%

Color and Shape:

Orange-red to brown, Powder

Molecular weight:

528.02