CAS 184095-69-0: (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi(3,5-dimethylphenyl)phosphine
Description:(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi(3,5-dimethylphenyl)phosphine is a chiral phosphine ligand notable for its application in asymmetric synthesis and catalysis. This compound features a ferrocenyl moiety, which contributes to its stability and steric properties, enhancing its effectiveness in coordination chemistry. The presence of diphenylphosphino groups provides strong donor capabilities, making it suitable for forming complexes with transition metals. The ethyl group in the structure adds to its steric bulk, influencing the ligand's reactivity and selectivity in catalytic processes. Additionally, the 3,5-dimethylphenyl substituents enhance the ligand's solubility and steric hindrance, which can be beneficial in various catalytic applications. The chirality of the compound allows for the potential to induce asymmetry in reactions, making it valuable in the synthesis of enantiomerically enriched compounds. Overall, this ligand exemplifies the intricate balance of sterics and electronics that is crucial in the design of effective catalysts in organic synthesis.
Formula:C40H40FeP2
InChI:InChI=1/C35H35P2.C5H5.Fe/c1-25-19-26(2)22-32(21-25)36(33-23-27(3)20-28(4)24-33)29(5)34-17-12-18-35(34)37(30-13-8-6-9-14-30)31-15-10-7-11-16-31;1-2-4-5-3-1;/h6-24,29H,1-5H3;1-5H;/t29-;;/m0../s1
- Synonyms:
- (R)-(-)-1-[(S)-2-Diphenylphosphino)ferrocenyl]ethylbis(3,5-dimethylphenyl)phosphine
- Josiphos SLJ005-1
- 1,2,3,4,5-cyclopentanepentayl, compd. with 1-[(1S)-1-[bis(3,5-dimethylphenyl)phosphino]ethyl]-2-(diphenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)

(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE
Ref: IN-DA003C28
1g | 91.00 € | ||
5g | 245.00 € | ||
100mg | 29.00 € | ||
250mg | 50.00 € |

(2R)-1-[(1R)-1-[Bis(3,5-dimethylphenyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene
Ref: 54-OR31031
5g | 455.00 € |

(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97% XyliPhos
Ref: 08-26-1255
2g | 1,254.00 € | ||
10g | 4,694.00 € | ||
100mg | 141.00 € | ||
500mg | 468.00 € |

(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi(3,5-xylyl)phosphine
Ref: 3D-FD170480
10mg | Discontinued | Request information | |
25mg | Discontinued | Request information | |
50mg | Discontinued | Request information | |
100mg | Discontinued | Request information | |
250mg | Discontinued | Request information |