CAS 199541-17-8: Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)

Description: Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II), with the CAS number 199541-17-8, is a complex coordination compound featuring ruthenium as the central metal ion. This compound is characterized by its intricate structure, which includes multiple ligands that enhance its stability and reactivity. The presence of dimethylammonium suggests a quaternary ammonium component, contributing to its solubility in polar solvents. The bis(diphenylphosphino) ligands provide strong coordination to the ruthenium center, influencing its electronic properties and potential catalytic activity. The dichloride and mu-chloro bridging ligands indicate a coordination environment that can facilitate various chemical transformations. This compound is of interest in the field of organometallic chemistry and catalysis, particularly for its potential applications in asymmetric synthesis and other catalytic processes. Its unique structural features and the presence of chiral ligands may also impart interesting optical properties, making it a subject of study in materials science and coordination chemistry.

Formula: (CH₃)₂NH₂C₈₈H₆₄Cl₅P₄R

Synonyms:

• (S)-[(RuCl(BINAP))2(μ-Cl)3][NH2Me2]
• Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(II)

[NH2Me2][(RuCl((S)-binap))2(μ-Cl)3]

CAS: 199541-17-8

• Formula: C₉₀H₇₂Cl₅NP₄Ru₂
• Color and Shape: Light yellow to Amber to Dark green powder to crystal
• Molecular weight: 1,670.86

Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH₂Me₂][{RuCl((S)-binap)}₂(μ-Cl)₃]

CAS: 199541-17-8

Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((S)-binap)}2(μ-Cl)3]

• Formula: (CH₃)₂NH₂C₈₈H₆₄Cl₅P₄Ru₂
• Color and Shape: orange pwdr.
• Molecular weight: 1669.83

Ruthenate(1-), bis[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]tri-μ-chlorodichlorodi-, stereoisomer, hydrogen, compd. with N-methylmethanamine (1:1:1)

CAS: 199541-17-8

• Formula: C₉₂H₈₀Cl₁₀N₂P₄Ru₄
• Purity: 80%
• Color and Shape: Solid
• Molecular weight: 2096.338

[NH2Me2][(RuCl((S)-binap))2(¼-Cl)3]

CAS: 199541-17-8

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• Formula: C₉₀H₇₂Cl₅NP₄Ru₂
• Purity: Min. 95%
• Molecular weight: 1,670.86 g/mol