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Di-tert-butyl azodicarboxylate, 98%
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Alfa Aesar By Thermo Fisher Scientific logo

Di-tert-butyl azodicarboxylate, 98%

CAS: 870-50-8

Ref. 02-L00294

5g
68.00 €
25g
199.00 €
Estimated delivery in United States, on Friday 10 May 2024

Product Information

Name:
Di-tert-butyl azodicarboxylate, 98%
Synonyms:
  • N-[(tert-butoxycarbonyl)imino](tert-butoxy)formamide
  • 1,2-Diazenedicarboxylic acid, 1,2-bis(1,1-dimethylethyl) ester
  • Azodicarboxylic acid di-tert-butyl ester
  • Bis(1,1-dimethylethyl)azodicarboxylate
  • Dbad
  • Di-Tert-Butyl Diazene-1,2-Dicarboxylate
  • Di-tert-butyl azodiformate
  • Di-tert-butyl diazodicarboxylate
  • Diazenedicarboxylic acid, bis(1,1-dimethylethyl) ester
  • Formic acid, azodi-, di-tert-butyl ester
  • See more synonyms
  • NSC 109889
  • di-tert-butyl (E)-diazene-1,2-dicarboxylate
Description:

Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates. It is also used in the electrophilic amination of beta-keto esters catalyzed by an axially chiral guanidine. It serves as a precursor in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such as L-proline or (S)-2-pyrrolidinyl tetrazole. It is also utilized in the asymmetric Friedel-Crafts amination through a chiral organocatalyst. Further, it acts as a reactant for preparation of hexapeptide key fragments through stereo selective selenocyclization/oxidative deselenylation reactions. In addition to this, it is employed as a starting material in the synthesis of pyrroloisoquinoline template through stereoselective N-acyliminium-mediated cyclization and enolate amination for preparation of peptidomimetic compounds and Barbier-type propargylation reactions. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Brand:
Alfa Aesar By Thermo Fisher Scientific
Long term storage:
Notes:

Chemical properties

Molecular weight:
230.26
Formula:
C10H18N2O4
Purity:
98%
Color/Form:
Yellow, Crystals or powder or crystalline powder or fused solid or flakes
InChI key:
QKSQWQOAUQFORH-UHFFFAOYSA-N
MDL:
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EINECS:
Merck:
HS code:

Hazard Info

UN Number:
EQ:
Class:
H Statements:
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Forbidden to fly:
Hazard Info:
Packing Group:
LQ:

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