(R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

CAS: 138124-32-0

Ref. 3D-FB30906

Product Information

• Name: (R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
• Synonyms: Jacobsen’s catalyst(R,R)-Jacobsen’s catalyst, (+)-Bis(3,5-Di-T-Bu-Salicyl.)-1,2-Cyclo-Hexanediamino-Mn Cl, (-)-Bis(3,5-Di-T-Bu-Salicyl.)-1,2-Cyclo-, (-)-Chloro{(1R,2R)-4,4′,6,6′-tetra-tert-butyl-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}manganese(III), (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-BIS(3,5-DI-T-Butylsalicylidene)]MANGANESE(III)CHLORIDE, (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-BIS(3,5-DI-T-Butylsalicylidene)]manganese (III) chloride, (R,R)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-diaminocyclohexylmanganese(III) chloride, (R,R)-(-)-N,N'-BIS(3.5-DI-T-Butylsalicylidene)-1,2-CYCLOHEXANEDIAMINE-manganese (III) chloride, (R,R)-(-)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino manganese(II) chloride, (R,R)-Jacobsen Cat., (R,R)-Jacobsen Catalyst, (R,R)-Jacobsen'S Catalyst, (R,R)-Jacobsen'S Catalyst Manganese(Iii) Chloride Complex, (R,R)-[N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride, (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-Butylsalicylidene)-1,2-Cyclohexanediamino-MANGANESE(III) CHLORIDE, (S,S)-Jacobsen Cat., (S,S)-Jacobsen Catalyst, (S,S)-Jacobsen'S Catalyst, (S,S)-Jacobsen'S Catalyst Manganese(Iii) Chloride Complex, (S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL-IDENE)-1,2-Cyclohexanediamino-MN-CL, (SP-5-13)-Chloro[[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]manganese, 2,2'-{(1R,2R)-cyclohexane-1,2-diylbis[nitrilo(E)methylylidene]}bis(4,6-di-tert-butylphenol)-trichloromanganese (1:1), 2,2'-{(1S,2S)-cyclohexane-1,2-diylbis[nitrilo(E)methylylidene]}bis(4,6-di-tert-butylphenol)-trichloromanganese (1:1), Jacobsen'S Catalyst, Manganese, chloro[[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]-, (SP-5-13)-, Manganese, chloro[[2,2′-[1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)phenolato]](2-)-N,N′,O,O′]-, [SP-5-13-(1R-trans)]-, Manganese, chloro[[2,2′-[1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]-, [SP-5-13-(1R-trans)]-, chloro[[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]manganese
• CAS: 138124-32-0

Description

(R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is a diamine ligand that has been used for the immobilization of ethylene. The reaction proceeds via an oxidation catalyzed by a metal such as copper or manganese. The reaction products are chlorides and alcohols. The molecular modeling and x-ray crystal structures of these reactions have been studied and kinetic data have been collected. Kinetics measurements show that the reactions are fast with an activation energy of 45 kcal/mol and proceed through a hydrogen transfer mechanism.

• Brand: Biosynth

Chemical properties

• Molecular weight: 635.2 g/mol
• Formula: C₃₆H₅₂ClMnN₂O₂
• Purity: Min. 95%
• Color/Form: Powder