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(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
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(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

CAS: 155830-69-6

Ref. 3D-FD179855

1g
163.00 €
2g
248.00 €
100mg
39.00 €
250mg
73.00 €
500mg
109.00 €
Estimated delivery in United States, on Monday 15 Jul 2024

Product Information

Name:
(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
Synonyms:
  • (R)1[(1S)2(diphenylphosphino)ferrocenyl] et-di-T-butylphosph
  • (R)-(-)-1-[(S)-2-Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
  • (R)-1-[(1S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
  • Josiphos SLJ002-1
  • 1,2,3,4,5-cyclopentanepentayl, compd. with 1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)
  • (R)-1-[(S)-2-(Dipheny1phosphino)ferroceny1] ethyldi-tert-butylphosphine
  • (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine
Description:

A novel, practical and efficient method for the preparation of (R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine is described. The asymmetric synthesis of ketones with high enantiomeric excess was achieved using this ligand in a one-pot, two-step procedure. The homogeneous catalytic reduction of nitriles to primary amines was also demonstrated. This methodology is applicable to the preparation of other chiral phosphines and phosphine derivatives.

Brand:
Biosynth
Long term storage:
Notes:

Chemical properties

Molecular weight:
542.5 g/mol
Formula:
C32H40FeP2
Purity:
Min. 98 Area-%
Color/Form:
Powder
MDL:
Melting point:
Boiling point:
Flash point:
Density:
Concentration:
EINECS:
Merck:
HS code:

Hazard Info

UN Number:
EQ:
Class:
H Statements:
P Statements:
Forbidden to fly:
Hazard Info:
Packing Group:
LQ:

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