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(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
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(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine

CAS: 55650-59-4

Ref. 3D-FD59975

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Estimated delivery in United States, on Monday 1 Jul 2024

Product Information

Name:
(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
Synonyms:
  • (S)-(R)-BPPFA
  • (2S)-1-[(1S)-1-(Dimethylamino)ethyl]-1′,2-bis(diphenylphosphino)ferrocene
  • (S)-N,N-Dimethyl-1-[(R)-1,2-bis(diphenylphosphino)ferrocenyl]ethylamine
  • (S,R)-1-(1-dimethylaminoethyl)-1,2-*bis(diphenyl
  • 1,2,3,4,5-cyclopentanepentayl, 1-[(1S)-1-(dimethylamino)ethyl]-2-(diphenylphosphino)-, compd. with 1-(diphenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)
  • Ferrocene, 1-[(1S)-1-(dimethylamino)ethyl]-1′,2-bis(diphenylphosphino)-, (2S)-
  • Ferrocene, 1-[1-(dimethylamino)ethyl]-1′,2-bis(diphenylphosphino)-, [S-(R*,R*)]-
Description:

(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine is a phosphine complex that has been used in asymmetric hydrogenation of β-unsaturated carbonyl compounds. The reaction takes place in the presence of a chiral binap ligand and a catalyst to give the desired product and the corresponding alcohol. The reactions are stereospecific, with high selectivity for the desired product. The catalytic system can be applied to various types of substrates, including esters and carboxylic acids, with good results. This reaction is often used when there is an interaction between phosphine and carboxylic acid groups on the same molecule.

Brand:
Biosynth
Long term storage:
Notes:

Chemical properties

Molecular weight:
625.5 g/mol
Formula:
C38H37FeNP2
Purity:
Min. 95%
MDL:
Melting point:
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Density:
Concentration:
EINECS:
Merck:
HS code:

Hazard Info

UN Number:
EQ:
Class:
H Statements:
P Statements:
Forbidden to fly:
Hazard Info:
Packing Group:
LQ:

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