Di-tert-butyl azodicarboxylate

CAS: 870-50-8

Ref. 3D-FD61002

Product Information

• Name: Di-tert-butyl azodicarboxylate
• Synonyms: Azodicarboxylic Acid Di-tert-butyl EsterDTAD, 1,2-Diazenedicarboxylic acid, 1,2-bis(1,1-dimethylethyl) ester, Azodicarboxylic acid di-tert-butyl ester, Bis(1,1-dimethylethyl)azodicarboxylate, Dbad, Di-Tert-Butyl Diazene-1,2-Dicarboxylate, Di-tert-butyl azodiformate, Di-tert-butyl diazodicarboxylate, Diazenedicarboxylic acid, bis(1,1-dimethylethyl) ester, Formic acid, azodi-, di-tert-butyl ester, NSC 109889, di-tert-butyl (E)-diazene-1,2-dicarboxylate
• CAS: 870-50-8

Description

Di-tert-butyl azodicarboxylate (DTBA) is an organic compound that is used in organic synthesis as a dienophile. DTBA reacts with various electrophiles to form dihydro derivatives through a transfer mechanism, which can be monitored by the change in magnetic resonance spectroscopy signals. The reaction of DTBA with trifluoroacetic acid and hydrogen chloride forms the desired product, 3-amino-2,4,6-trichloropyridine. DTBA is also used for the synthesis of 1,4-dihydropyridines from 2-aminobenzene derivatives and bromoacetaldehyde diethyl acetal. This process is catalyzed by palladium on carbon. DTBA is asymmetric at position C5 and C6 because it has two chiral centers: one at C3 and one at C5 or C6. The use of this reagent allows for the scalable

• Brand: Biosynth

Chemical properties

• Molecular weight: 230.26 g/mol
• Formula: C₁₀H₁₈N₂O₄
• Purity: Min. 98%
• Color/Form: Powder
• InChI: InChI=1S/C10H18N2O4/c1-9(2,3)15-7(13)11-12-8(14)16-10(4,5)6/h1-6H3/b12-11+
• InChI key: InChIKey=QKSQWQOAUQFORH-VAWYXSNFSA-N
• SMILES: CC(C)(C)OC(=O)/N=N/C(=O)OC(C)(C)C