Di-1-adamantylphosphine
CAS: 131211-27-3
Ref. 3D-GFA21127
| 1g | Discontinued | ||
| 5g | Discontinued | ||
| 10g | Discontinued | ||
| 250mg | Discontinued | ||
| 500mg | Discontinued | ||
| 2500mg | Discontinued |
Product Information
- Bis(adamant-1-yl)phosphine
- Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine
- Bis(tricyclo[3.3.1.1<sup>3,7</sup>]dec-1-yl)phosphine
- Diadamantylphosphine
- Phosphine, bis(tricyclo[3.3.1.1<sup>3,7</sup>]dec-1-yl)-
- Phosphine, bis(tricyclo[3.3.1.13,7]dec-1-yl)-
Di-1-adamantylphosphine (DAP) is a coordination compound that belongs to the group of organophosphorus compounds. DAP is a catalyst in organic reactions and has been used as a homogeneous catalyst for the synthesis of aryl chlorides from aryl halides, such as benzyl chloride. DAP binds to the metal center using its two phosphines and forms an adduct with the metal center. The formation of this adduct may be due to hydrogen bonding or an intermolecular hydrogen bond. The reaction mechanism of DAP is not well understood, but it has been proposed that electron transfer occurs between the metal center and one of its ligands which results in the removal of chloride from one of them. This process produces a new ruthenium complex, which can then react with another molecule to form another ruthenium complex.
