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(S)-3,3'-Bis(diphenylphosphanyl)-[1,1'-binapthalene]-2,2'-diol
CAS: 911383-51-2
Ref. 3D-LLB38351
| 500mg | To inquire |
Product Information
(S)-3,3'-Bis(diphenylphosphanyl)-[1,1'-binapthalene]-2,2'-diol is an aniline that can be synthesized from terminal alkynes and palladium complexes. This compound has been shown to catalyze the asymmetric ring-opening of some heterocycles such as pyridines or quinolines. The mechanistic pathway of this reaction is rationalized by a proton transfer from the nucleophile to the electrophile. The enantiopure product was obtained in high yield with a high degree of stereoselectivity. The synthesis of amines and epoxides were also possible using this catalyst.
Chemical properties
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