Di-¼-chloro-tetracarbonyldirhodium(I)

CAS: 14523-22-9

Ref. 3D-PAA52322

Product Information

• Name: Di-¼-chloro-tetracarbonyldirhodium(I)
• Synonyms: Bis(chlororhodiumdicarbonyl), Bis(dicarbonyl(μ-chloro)rhodium), Bis(dicarbonylchlororhodium), Bis(dicarbonylrhodium chloride), Bis(μ-chloro)bis(dicarbonylrhodium), Carbon Monoxide, Chlorodicarbonylrhodium dimer, Chlorodicarbonylrhodium(I) dimer, Chlororhodium dicarbonyl dimer, Di-Mu-Chloro-Bis(Dicarbonylrhodium), Di-My-Chloro-Tetracarbonyldirhodium, Di-mu-chloro-tetracarbonyldirhodium, Di-Μ-Chloro-Bis(Dicarbonylrhodium), Di-Μ-Cloro-Bis(Dicarbonilrodio), Di-μ-Chlorotetracarbonyldirhodium(I), Di-μ-chlor-bis(dicarbonylrhodium), Dicarbonylchlororhodium dimer, Dicarbonylrhodium chloride dimer, Dichloride, Dichlorodirhodiumtetracarbonyl, Dichlorotetracarbonyldirhodium, Dirhodium tetracarbonyl dichloride, Nsc 120116, Rhodium carbonyl chloride, Rhodium carbonyl chloride (Rh2(CO)4Cl2), Rhodium carbonyl chloride (Rh₂(CO)₄Cl₂), Rhodium carbonyl chloride dimer, Rhodium dicarbonyl chloride dimer, Rhodium(+1) Cation, Rhodium, tetracarbonyldi-μ-chlorodi-, Tetracarbonyl-μ,μ'-dichlorodirhodium, Tetracarbonyl-μ,μ'-dichlorodirhodium(I), Tetracarbonylbis(μ-chloro)dirhodium, Tetracarbonyldi-μ-chlorodirhodium, Tetracarbonyldichlorodirhodium, [Rh(CO)2Cl]2, tetracarbonyldi-U-chlorodirhodium(I), μ-Dichlorotetracarbonyldirhodium
• CAS: 14523-22-9

Description

Di-¼-chloro-tetracarbonyldirhodium(I) is a compound that has been shown to catalyze the carbonylation of various organic substrates in the presence of oxygen. In the presence of a catalytic amount of di-¼-chloro-tetracarbonyldirhodium(I), aniline was converted to 4,4'-dichlorobenzophenone with a yield of 43%. The same reaction also produced 3,3'-dichlorobenzophenone and 2,2'-dichlorobenzophenone as side products. The compound was obtained by reacting hexanes with chlorodirhodium trichloride in the presence of air. The structural analysis was performed using x-ray diffraction technique on an orange powder. It was found that the compound crystallizes in a monoclinic space group with unit cell dimensions a=7.5 Å

• Brand: Biosynth

Chemical properties

• Molecular weight: 388.76 g/mol
• Formula: C₄Cl₂O₄Rh₂
• Purity: Min. 95%