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CYCLOTRIMETHYLENEDICHLOROSILANE
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CYCLOTRIMETHYLENEDICHLOROSILANE

CAS: 2351-33-9

Ref. 3H-SIC2568.0

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50gTo inquire
Estimated delivery in United States, on Tuesday 4 Jun 2024

Product Information

Name:
CYCLOTRIMETHYLENEDICHLOROSILANE
Synonyms:
  • 1,1-DICHLOROSILACYCLOBUTANE
  • 1,1-Dichloro-1-silacyclobutane
  • 1,1-Dichlorosiletane
  • Cyclotrimethylenedichlorosilane
  • Silacyclobutane, 1,1-dichloro-
Description:

Silane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Cyclotrimethylenedichlorosilane; 1,1-Dichlorosilacyclobutane
Reaction with LiN(iPr)2 and CH2X2 provides 1,1-dimethyl-2-halosilacyclopentanesArylchlorosilyl derivatives used in cross-coupling to biarylsVinylchlorosilyl derivatives used in cross-coupling to 1,3-butadienesStarting material for spirocyclic organosilanesPrecursor for aryl-substituted silacyclobutanes useful for aryl cross-coupling reactionsExtensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

Brand:
Gelest
Long term storage:
Notes:

Chemical properties

Molecular weight:
141.07
Formula:
C3H6Cl2Si
Purity:
97%
Color/Form:
Straw Liquid
MDL:
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Concentration:
EINECS:
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Hazard Info

UN Number:
EQ:
Class:
H Statements:
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Forbidden to fly:
Hazard Info:
Packing Group:
LQ:

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