VINYLTRIMETHYLSILANE
CAS: 754-05-2
Ref. 3H-SIV9250.0
| 10g | To inquire | |
| 100g | To inquire | |
| 13kg | To inquire | |
| 1.5kg | To inquire |
Product Information
- (Trimethylsilyl)ethene
- (Trimethylsilyl)ethylene
- Ethenyltrimethylsilane
- Nsc 93553
- Silane, Trimethylvinyl
- Trimethyl(vinyl)silane
- Trimethylvinylsilan
- Trimethylvinylsilane
- Trimetilvinilsilano
- Vinyltrimethylsilane
- See more synonyms
- W 139
Alkenylsilane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Vinyltrimethylsilane; Ethenyltrimethylsilane; Trimethylsilylethene; Trimethylvinylsilane
Viscosity, 20 °C: 0.5 cStΔHcomb: 4,133 kJ/molΔHfus: 7.7 kJ/molCopolymerization parameters- e,Q: 0.04, 0.029Forms polymers which can be fabricated into oxygen enrichment membranesPolymerization catalyzed by alkyllithium compoundsReacts w/ azides to form trimethylsilyl-substituted aziridinesUndergoes Heck coupling to (E)-β-substituted vinyltrimethylsilanes, which can then be cross-coupled furtherExtensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
Chemical properties
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