1-ETHOXYVINYLTRI-n-BUTYLTIN
CAS: 97674-02-7
Ref. 3H-SNE4620
| 25g | Discontinued | ||
| 2kg | Discontinued | ||
| 20kg | Discontinued |
Product Information
- Tributyl-(1-ethoxyvinyl)tin
- Ethoxyvinyltrinbutyltin
- Tributyl(1-Ethoxyethenyl)Stannane
Organotin Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
1-Ethoxyvinyltri-n-butyltin; Tri-n-butyl(1-ethoxyvinyl)stannane
Transfer of acyl group equivalent in Stille CouplingCan be cross-coupled with aryl chloridesUsed to acylate aryl triflatesUndergoes Stille cross-coupling reactions as employed in the syntheses of three cladiellinsCross-couples with vinyl sulfidesCan be cross-coupled with heteroaromatic chloridesExtensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
