Product Information
- (Ethenyl)tributyltin
- (Tributylstannyl)ethene
- (Tributylstannyl)ethylene
- Ethenyltributylstannane
- Stannane, tributylethenyl-
- Stannane, tributylvinyl-
- Tin Vinyl Tributyl
- Tin, tributylvinyl-
- Tributilvinilestannano
- Tributyl(Ethenyl)Stannane
- See more synonyms
- Tributyl(vinyl)tin
- Tributylethenylstannane
- Tributylvinylstannan
- Tributylvinyltin
- Vinyltri-n-butyltin
- Vinyltributylstannane
- Vinyltributyltin
Organotin Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Vinyltri-n-butyltin; Tributylethenylstannane; Tributylvinylstannane
Copolymerization parameters - e,Q: 0.800, 0.024Stille Coupling vinylation reagentIntermediate for vinyllithium by exchange with phenyllithiumWith CO forms divinyl ketones on reaction with vinyl iodidesReacts with IC6H4CHO in DMF with PdCl2(CH3CN)2 to yield CH2=CHC6H4CHOReacts with halopyrimidines to yield vinylpyrimidinesEmployed in one-pot synthesis of pyrrolesExtensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
