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VINYLTRI-n-BUTYLTIN
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VINYLTRI-n-BUTYLTIN

CAS: 7486-35-3

Ref. 3H-SNV9100

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Estimated delivery in United States, on Friday 24 May 2024

Product Information

Name:
VINYLTRI-n-BUTYLTIN
Synonyms:
  • (Ethenyl)tributyltin
  • (Tributylstannyl)ethene
  • (Tributylstannyl)ethylene
  • Ethenyltributylstannane
  • Stannane, tributylethenyl-
  • Stannane, tributylvinyl-
  • Tin Vinyl Tributyl
  • Tin, tributylvinyl-
  • Tributilvinilestannano
  • Tributyl(Ethenyl)Stannane
  • See more synonyms
  • Tributyl(vinyl)tin
  • Tributylethenylstannane
  • Tributylvinylstannan
  • Tributylvinyltin
  • Vinyltri-n-butyltin
  • Vinyltributylstannane
  • Vinyltributyltin
Description:

Organotin Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Vinyltri-n-butyltin; Tributylethenylstannane; Tributylvinylstannane
Copolymerization parameters - e,Q: 0.800, 0.024Stille Coupling vinylation reagentIntermediate for vinyllithium by exchange with phenyllithiumWith CO forms divinyl ketones on reaction with vinyl iodidesReacts with IC6H4CHO in DMF with PdCl2(CH3CN)2 to yield CH2=CHC6H4CHOReacts with halopyrimidines to yield vinylpyrimidinesEmployed in one-pot synthesis of pyrrolesExtensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

Brand:
Gelest
Long term storage:
Notes:

Chemical properties

Molecular weight:
317.08
Formula:
C14H30Sn
Purity:
97%
Color/Form:
Straw Liquid
MDL:
Melting point:
Boiling point:
Flash point:
Density:
Concentration:
EINECS:
Merck:
HS code:

Hazard Info

UN Number:
EQ:
Class:
H Statements:
P Statements:
Forbidden to fly:
Hazard Info:
Packing Group:
LQ:

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