(Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-KappaN,KappaP](Eta5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate
CAS: 930601-66-4
Ref. TR-A164155
1mg | 92.00 € | ||
5mg | 101.00 € | ||
10mg | 119.00 € |
Product Information
- (Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-?N,?P](?5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate
Applications (Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-κN,κP](η5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate, is an Alkene Zipper Catalyst, used in selective transformation of a large variety of ω-alkenyl cyclopropylcarbinols into stereodefined unconjugated (E)-acyclic aldehydes .
References Bruffaerts, J., Vasseur, A., & Marek, I. (2018). Alkene-Zipper Catalyzed Selective and Remote Retro-ene Reaction of Alkenyl Cyclopropylcarbinol. Advanced Synthesis & Catalysis, 360(7), 1389-1396.
Chemical properties
Technical inquiry about: TR-A164155 (Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-KappaN,KappaP](Eta5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate
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