[1(Z),2E,8[2S,3S(1S,2S)]]- 5,9-Anhydro-2,3,4,8-tetradeoxy-8-[[3-(2-hydroxy-1-methylpropyl)oxiranyl]methyl]-3-methyl-L-talo-Non-2-enonic Acid 9-Methoxy-9-oxo-5-nonenyl Ester

CAS: 89254-47-7

Ref. TR-A656025

Product Information

• Name: [1(Z),2E,8[2S,3S(1S,2S)]]- 5,9-Anhydro-2,3,4,8-tetradeoxy-8-[[3-(2-hydroxy-1-methylpropyl)oxiranyl]methyl]-3-methyl-L-talo-Non-2-enonic Acid 9-Methoxy-9-oxo-5-nonenyl Ester

Description

Applications [1(Z),2E,8[2S,3S(1S,2S)]]- 5,9-Anhydro-2,3,4,8-tetradeoxy-8-[[3-(2-hydroxy-1-methylpropyl)oxiranyl]methyl]-3-methyl-L-talo-Non-2-enonic Acid 9-Methoxy-9-oxo-5-nonenyl Ester is an intermediate in the synthesis of Pseudomonic Acid D Sodium (P839520) an antibiotic isolated from Pseudomonas fluorescens.
References Banks, R.M., et al.: J. Antibiot., 41, 609 (1988),

• Brand: TRC

Chemical properties

• Molecular weight: 516.524
• Formula: C₂₇H₄₄O₉
• Color/Form: White Solid
• InChI: InChI=1S/C23H24N4O8S/c1-11-5-7-15(8-6-11)36-21-17-20(25-23(31)26-21)27(10-24-17)22-19(34-14(4)30)18(33-13(3)29)16(35-22)9-32-12(2)28/h5-8,10,16,18-19,22H,9H2,1-4H3,(H,25,26,31)/t16-,18?,19?,22-/m1/s1
• InChI key: InChIKey=FGOSQAPWZULDRY-PZNXAURZSA-N
• SMILES: CC(=O)OC[C@H]1O[C@@H](n2cnc3c(Sc4ccc(C)cc4)nc(=O)[nH]c32)C(OC(C)=O)C1OC(C)=O