(R,R)-(-)-N,N’-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

CAS: 135616-40-9

Ref. TR-B431500

Product Information

• Name: (R,R)-(-)-N,N’-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
• Synonyms: (1R,2R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine, (R,R)-2,2'-[(1,2-Cyclohexanediyl)bis(nitrilomethylidyne)]bis[4,6-di(tert-butyl)phenol], 2,2'-[(1R,2R)-1,2-Cyclohexanediylbis[(E)-nitrilomethylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenol, (-)-N,N′-Bis((E)-3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine, (1R,2R)-(-)-1,2-Cyclohexanediamino-N N'-Bis(3,5-Di-T-Butylsalicylidene), (1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-Bis-(3,5-Di-Tert-Butylsalicylidene), (1R,2R)-(-)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine, (R,R)-(-)-N,N'-Bis(3,5-Di-T-Bu-Salicyl.)-1 ,2-Cyclohexandiam., (R,R)-(-)-N,N'-Bis(3,5-di-t-bu-salicyl.)-1,2-cyclohexanedia, (R,R)-(-)-N,N'-Bis(3.5-Di-T-Butylsalicylidene)-1,2-Cyclohexanediamine, (R,R)-2,2′-[(1,2-Cyclohexanediyl)bis(nitrilomethylidyne)]bis[4,6-di(tert-butyl)phenol], (R,R)-Jacobsen Ligand, (R,R)-Jacobsen'S Ligand, 2,2′-[(1R,2R)-1,2-Cyclohexanediylbis[(E)-nitrilomethylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenol, 6,6'-[(1R,2R)-cyclohexane-1,2-diylbis(iminomethylylidene)]bis(2,4-di-tert-butylcyclohexa-2,4-dien-1-one), Phenol, 2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(E)-nitrilomethylidyne]]bis[4,6-bis(1,1-dimethylethyl)-, Phenol, 2,2′-[1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)-, [1R-[1α(E),2β(E)]]-

Description

Applications (R,R)-(-)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine is a versatile ligand used in the preparation of Jacobsen's catalyst.
References Jacobsen, E.N. et al.: J. Am. Chem. Soc., 113, 7063 (1991); Deng, L. et al.: J. Org. Chem., 57, 4320 (1992);

• Brand: TRC

Chemical properties

• Molecular weight: 546.83
• Formula: C₃₆H₅₄N₂O₂
• Color/Form: Neat
• InChI: InChI=1S/C36H54N2O2/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12/h17-22,29-30,37-38H,13-16H2,1-12H3/b23-21-,24-22+/t29-,30-/m1/s1
• InChI key: InChIKey=FGIQYENVFXNDTF-REPODWTJSA-N
• SMILES: CC(C)(C)C1=C/C(=C/N[C@@H]2CCCC[C@H]2N/C=C2\C=C(C(C)(C)C)C=C(C(C)(C)C)C2=O)C(=O)C(C(C)(C)C)=C1