(tert-​Butoxycarbonylmethyl​ene)​triphenylphosphorane

CAS: 35000-38-5

Ref. TR-B943165

Product Information

• Name: (tert-​Butoxycarbonylmethyl​ene)​triphenylphosphorane
• Synonyms: Acetic acid, 2-(triphenylphosphoranylidene)-, 1,1-dimethylethyl ester, Acetic acid, (triphenylphosphoranylidene)-, 1,1-dimethylethyl ester (9CI), (Triphenyl-?5-phosphanylidene)acetic acid tert-butyl ester, (Triphenylphosphoranylidene)acetic acid tert-butyl ester, (tert-Butoxycarbonylmethylene)triphenylphosphoran, (tert-Butoxycarbonylmethylene)triphenylphosphorane, 1,1-Dimethylethyl (triphenylphosphoranylidene)acetate, 1,1-Dimethylethyl 2-(triphenyl-?5-phosphanylidene)acetate, NSC 82469, Triphenyl(tert-butoxycarbonylmethylene)phosphorane, tert-Butyl (triphenylphosphoranylidene)acetate, tert-Butyl 2-(triphenylphosphaneylidene)acetate, tert-Butyl 2-(triphenylphosphoranylidene)acetate, tert-Butyl triphenylphosphoranylidenacetate, GR 44557X, Lacidipine related, (Triphenyl-λ⁵-phosphanylidene)acetic acid tert-butyl ester, 1,1-Dimethylethyl 2-(triphenyl-λ5-phosphanylidene)acetate, Acetic acid, (triphenylphosphoranylidene)-, 1,1-dimethylethyl ester, Acetic acid, 2-(triphenylphosphoranylidene)-, 1,1-dimethylethyl ester, Tert-Butyl (Triphenyl-Lambda~5~-Phosphanylidene)Acetate, tert-Butyl (triphenylphosphoranylidene)acetate~(Carbo-tert-butoxymethylene)triphenylphosphorane

Description

Applications (tert-​Butoxycarbonylmethyl​ene)​triphenylphosphorane is a reactant used as a catalyst in the synthesis of indanols as well as α,​β-​unsatd. fatty acids.
References Loesche, A. et al.: Bioorg. Med Chem. Lett., 28, 3315 (2018); Panchal, H. et al.: Chem. Comm., 54, 12389 (2018);

• Brand: TRC

Chemical properties

• Molecular weight: 376.43
• Formula: C₂₄H₂₅O₂P
• Color/Form: Neat
• InChI: InChI=1S/C24H25O2P/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22/h4-19H,1-3H3
• InChI key: InChIKey=ZWZUFQPXYVYAFO-UHFFFAOYSA-N
• SMILES: CC(C)(C)OC(=O)C=P(c1ccccc1)(c1ccccc1)c1ccccc1